{"id":"W2996255642","doi":"10.1139/cjc-2019-0371","title":"The chemistry of biguanides: from synthetic routes to applications in organic chemistry","year":2019,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis and Characterization of Heterocyclic Compounds","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada; Université de Montréal","keywords":"Chemistry; Catalysis; Organometallic chemistry; Combinatorial chemistry; Organic chemistry; Triazine; Computational chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001681596,0.0002371916,0.0004079173,0.00003101618,0.000107868,0.00009253027,0.0009980709,0.0002050639,0.01790703],"category_scores_gemma":[0.0002506043,0.0002071538,0.000175666,0.0002397954,0.0001065394,0.00007230654,0.00004375082,0.0003750529,0.00002305402],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002976237,"about_ca_system_score_gemma":0.0008481402,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003034024,"about_ca_topic_score_gemma":0.0002000564,"domain_scores_codex":[0.9982643,0.000009650455,0.0008184469,0.0002659532,0.0002718951,0.0003698307],"domain_scores_gemma":[0.9977691,0.0003169125,0.0005109626,0.0006799416,0.0001996512,0.0005234614],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001697322,0.00002971427,0.009329591,0.0001564156,0.00005491139,0.000008840175,0.0001769037,0.00001823009,0.9886245,0.000002319544,0.00012271,0.001458873],"study_design_scores_gemma":[0.0003198409,0.000003995649,0.001042239,0.0003019185,0.00002506276,0.00003787572,0.001413769,0.00001955408,0.9253114,0.0001085063,0.0711839,0.0002318683],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9857191,0.0005835037,0.00002512089,0.0005825409,0.00006906896,0.00005746308,0.00009080264,0.00000911434,0.01286331],"genre_scores_gemma":[0.9959795,0.00003657988,0.00004368723,0.00003713787,0.0002549933,0.00001252607,0.00003005559,0.0000383282,0.003567148],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07106119,"threshold_uncertainty_score":0.9829907,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005216450288254175,"score_gpt":0.1905574512473182,"score_spread":0.1853410009590641,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}