{"id":"W2997093228","doi":"10.1002/marc.201900468","title":"Synthesis and Post‐Polymerization Functionalization of Halogen‐Substituted Polyphosphinoboranes to Access Alkyne‐Functionalized Derivatives","year":2019,"lang":"en","type":"article","venue":"Macromolecular Rapid Communications","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Engineering and Physical Sciences Research Council; Alexander von Humboldt-Stiftung","keywords":"Sonogashira coupling; Surface modification; Halogen; Alkyne; Polymer chemistry; Phosphine; Chemistry; Polymerization; Boranes; Yield (engineering); Catalysis; Polymer; Combinatorial chemistry; Materials science; Organic chemistry; Palladium; Boron; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001128654,0.0004031732,0.0001447274,0.0001180108,0.0001078216,0.0001508351,0.0001818731,0.0001971042,0.001649617],"category_scores_gemma":[0.0001177945,0.0001673352,0.0001419332,0.0001027087,0.0001398309,0.0002192022,0.0001721339,0.0003897946,0.0004408913],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001929383,"about_ca_system_score_gemma":0.0001989817,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004048256,"about_ca_topic_score_gemma":0.0009201742,"domain_scores_codex":[0.9999347,0.000008695923,0.000004204332,0.0000135045,0.00001285277,0.00002607281],"domain_scores_gemma":[0.999945,0.00000952855,0.00001327111,0.000006815608,0.000006401261,0.00001890697],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003818017,0.00001085802,0.00002565957,0.00003724093,0.000003103909,0.00005565098,0.00001811562,0.000104901,0.9985465,0.000144939,0.00003193552,0.0009827776],"study_design_scores_gemma":[0.00001030363,0.0001035742,0.000446659,0.000002319929,0.000003851571,0.00006704675,0.000006813009,0.0002445753,0.997739,0.00002824606,0.001343573,0.000004074974],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9866789,0.001032288,0.007062233,0.00008221177,0.00004225548,0.00005562727,0.0002992511,0.0001340245,0.004613216],"genre_scores_gemma":[0.9924471,0.0006633934,0.004218131,0.00003440665,0.00000768634,0.00003039415,0.0002160991,0.00002600972,0.002356747],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001649617,"threshold_uncertainty_score":0.005518496,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01420118400031898,"score_gpt":0.2538649796412729,"score_spread":0.2396637956409539,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}