{"id":"W2998034031","doi":"10.1039/c9cc09347h","title":"Palladium-catalyzed aerobic synthesis of <i>ortho</i>-substituted phenols from cyclohexanones and primary alcohols","year":2020,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Higher Education Discipline Innovation Project; National Natural Science Foundation of China; Canada Research Chairs; Lanzhou University","keywords":"Catalysis; Palladium; Phenols; Primary (astronomy); Chemistry; Organic chemistry; Medicinal chemistry; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001336274,0.0002143848,0.0004301948,0.00003460365,0.000119844,0.00003503656,0.0009517596,0.0001769019,0.0006643414],"category_scores_gemma":[0.001435807,0.0002338306,0.0001241644,0.000341489,0.0004949634,0.0001264368,0.0007162328,0.000289738,0.00002623019],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005523911,"about_ca_system_score_gemma":0.0001055682,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000653496,"about_ca_topic_score_gemma":0.000005008494,"domain_scores_codex":[0.9985554,0.00006526145,0.0005865286,0.0003721238,0.0002434912,0.0001772279],"domain_scores_gemma":[0.9957005,0.002062568,0.0002532872,0.001613403,0.0001486509,0.0002215509],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004427218,0.0001144549,0.001233646,0.0001008981,0.0001385686,5.878436e-7,0.0002212923,0.000005506205,0.9947046,0.001032587,0.0003679772,0.002035599],"study_design_scores_gemma":[0.0006723272,0.00000257447,0.0007511374,0.00009719309,0.0002663815,0.000005729719,0.0001272345,0.0006900787,0.9780705,0.0005913275,0.01840062,0.0003248912],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9342315,0.003981826,0.00415321,0.007134808,0.00005011227,0.0003211981,0.0008603479,0.0004480283,0.04881901],"genre_scores_gemma":[0.9544236,0.0005445873,0.04222679,0.0003907486,0.00009335556,0.0001160857,0.002093758,0.00004554537,0.00006551067],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0487535,"threshold_uncertainty_score":0.9535335,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05013976889556606,"score_gpt":0.277785533095449,"score_spread":0.2276457641998829,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}