{"id":"W2999969233","doi":"10.1111/php.13212","title":"Theoretical Study of the Wavelength Selection for the Photocleavage of Coumarin‐caged D‐luciferin","year":2020,"lang":"en","type":"article","venue":"Photochemistry and Photobiology","topic":"bioluminescence and chemiluminescence research","field":"Biochemistry, Genetics and Molecular Biology","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Core Research for Evolutional Science and Technology; Japan Society for the Promotion of Science; New Energy and Industrial Technology Development Organization","keywords":"Luciferin; Conformational isomerism; Chemistry; Excited state; Photochemistry; Moiety; Aqueous solution; Wavelength; Visible spectrum; Stereochemistry; Physical chemistry; Molecule; Organic chemistry; Atomic physics; Materials science; Physics; Optoelectronics; Luciferase","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002997821,0.0003788952,0.0004100558,0.0004400077,0.0005385448,0.0003700173,0.0006716141,0.0006278819,0.002821327],"category_scores_gemma":[0.0006234227,0.0003093866,0.0005590541,0.0003005184,0.0005982145,0.0004826456,0.0002857385,0.0003756826,0.0002496559],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0009268771,"about_ca_system_score_gemma":0.0006376271,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004059158,"about_ca_topic_score_gemma":0.00248761,"domain_scores_codex":[0.9999125,0.00001687373,0.000002012259,0.00001380345,0.0000272083,0.00002756762],"domain_scores_gemma":[0.9998081,0.0001160789,0.00001808526,0.00001267865,0.00003217547,0.00001278918],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"theoretical_or_conceptual","study_design_scores_codex":[0.00008108645,0.00008007843,0.001722395,0.0001924647,0.00002478498,0.0003917735,0.0001144162,0.9134063,0.02492589,0.05189042,0.0006240721,0.006546391],"study_design_scores_gemma":[0.00001270328,0.00001930886,0.0004793894,0.00000658462,0.000006887329,0.00002577691,0.00002783838,0.9941188,0.001494773,0.003547449,0.0002535938,0.000006833249],"study_design_candidate":"theoretical_or_conceptual","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7928171,0.0009230829,0.1647447,0.0007569114,0.00006227207,0.00009040181,0.0002566797,0.0001914765,0.04015744],"genre_scores_gemma":[0.9882762,0.0003290715,0.008968581,0.00007932559,0.000008968871,0.0001075661,0.00008981423,0.00005311729,0.002087368],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004059158,"threshold_uncertainty_score":0.009438276,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01736607579061851,"score_gpt":0.2684367811437343,"score_spread":0.2510707053531158,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}