{"id":"W3000966424","doi":"10.1039/c9an02192b","title":"Analysis of multi-electron, multi-step homogeneous catalysis by rotating disc electrode voltammetry: theory, application, and obstacles","year":2020,"lang":"en","type":"article","venue":"The Analyst","topic":"Electrocatalysts for Energy Conversion","field":"Energy","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"Toronto Metropolitan University","funders":"Basic Energy Sciences; Office of Science; University of North Carolina; Alfred P. Sloan Foundation; U.S. Department of Energy; David and Lucile Packard Foundation; National Science Foundation","keywords":"Homogeneous; Electrode; Voltammetry; Cyclic voltammetry; Electron; Catalysis; Analytical Chemistry (journal); Chemistry; Materials science; Electrochemistry; Physics; Physical chemistry; Chromatography; Thermodynamics; Organic chemistry; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001667489,0.000551199,0.001043087,0.0005609609,0.0002276039,0.001124862,0.002209307,0.001244425,0.0005057797],"category_scores_gemma":[0.002889912,0.0004252047,0.0005117516,0.000721026,0.0007341687,0.00151003,0.0005753573,0.001383598,0.0002370433],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008062857,"about_ca_system_score_gemma":0.0005862623,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008711026,"about_ca_topic_score_gemma":0.0006755331,"domain_scores_codex":[0.9993644,0.000141037,0.00004183635,0.0001368292,0.0002714437,0.00004449105],"domain_scores_gemma":[0.9989164,0.000727246,0.00005716834,0.0001482397,0.000133365,0.00001759891],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002153827,0.0003382902,0.005412176,0.00304404,0.0002218871,0.0010543,0.0004496009,0.233999,0.351075,0.1269218,0.001336111,0.2759323],"study_design_scores_gemma":[0.00001848333,0.0002120576,0.001553869,0.00005170096,0.0000284138,0.0003083648,0.0001072179,0.8136661,0.1535177,0.02615692,0.004335755,0.00004337772],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.1161137,0.006455295,0.8721192,0.0007821148,0.00005432951,0.0001261544,0.000147768,0.0005502115,0.003651132],"genre_scores_gemma":[0.7792842,0.008249097,0.2105206,0.0001298092,0.00003704815,0.0001797309,0.0001908324,0.0000577944,0.001350824],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.002209307,"threshold_uncertainty_score":0.008818626,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0094900815212707,"score_gpt":0.2340050169598615,"score_spread":0.2245149354385908,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}