{"id":"W3001152697","doi":"10.1002/anie.201915875","title":"Switch in Selectivity for Formal Hydroalkylation of 1,3‐Dienes and Enynes with Simple Hydrazones","year":2020,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":61,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Killam Trusts; Canada Foundation for Innovation; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; McGill University","keywords":"Markovnikov's rule; Catalysis; Regioselectivity; Allylic rearrangement; Combinatorial chemistry; Chemistry; Selectivity; Steric effects; Ruthenium; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001527864,0.000122248,0.0001644073,0.0000695403,0.00004167564,0.00002210879,0.00008352916,0.00007961105,0.0003080824],"category_scores_gemma":[0.0003640168,0.0001205592,0.0000433292,0.0001527485,0.00005072555,0.0004532253,0.00003707531,0.00007928735,8.675295e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006888965,"about_ca_system_score_gemma":0.00004296012,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006229502,"about_ca_topic_score_gemma":0.00007622447,"domain_scores_codex":[0.9990878,0.000006469354,0.0002650193,0.0002537197,0.0002606223,0.0001263729],"domain_scores_gemma":[0.9992235,0.0002383227,0.0001754543,0.00007304326,0.000237671,0.00005203925],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001073953,0.0001646625,0.0429915,0.0004657612,0.0001262789,0.000002567968,0.001001991,0.001184818,0.9436088,0.00158604,0.001486645,0.006307005],"study_design_scores_gemma":[0.00129093,0.00005029748,0.003319832,0.0000428354,0.00002571989,0.00001013637,0.0001598238,0.009175081,0.9793985,0.001613132,0.004772542,0.0001411071],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8298159,0.00009169986,0.1632078,0.001860863,0.0001704011,0.0002137034,0.000303194,0.00007877372,0.004257642],"genre_scores_gemma":[0.9964024,0.0000220306,0.001547061,0.0001160426,0.0006405266,0.00007042103,0.001105426,0.00001696888,0.00007914981],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1665865,"threshold_uncertainty_score":0.4916263,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02201270636551868,"score_gpt":0.2754321667760629,"score_spread":0.2534194604105443,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}