{"id":"W3002047432","doi":"10.1039/c9em00583h","title":"Isotope fractionation (<sup>2</sup>H/<sup>1</sup>H, <sup>13</sup>C/<sup>12</sup>C, <sup>37</sup>Cl/<sup>35</sup>Cl) in trichloromethane and trichloroethene caused by partitioning between gas phase and water","year":2020,"lang":"en","type":"article","venue":"Environmental Science Processes & Impacts","topic":"Chemical Reactions and Isotopes","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Toronto Public Health","funders":"H2020 Marie Skłodowska-Curie Actions; Natural Sciences and Engineering Research Council of Canada; Horizon 2020 Framework Programme","keywords":"Isotope; Radiochemistry; Fractionation; Chemistry; Physics; Nuclear physics; Chromatography","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002113835,0.0003014165,0.0001947194,0.0002600109,0.0002275199,0.0003214025,0.0002964697,0.0003123596,0.0008309801],"category_scores_gemma":[0.0003363461,0.0001395292,0.0002832623,0.0002803932,0.000303613,0.0002906415,0.0002658485,0.0003056993,0.0002382001],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006340496,"about_ca_system_score_gemma":0.0002799685,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003954224,"about_ca_topic_score_gemma":0.004788527,"domain_scores_codex":[0.9998292,0.00001652408,0.000007626646,0.00005437376,0.00006476809,0.00002752528],"domain_scores_gemma":[0.9998513,0.00005053781,0.0000282384,0.00001102052,0.00004918331,0.000009600131],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000148601,0.00000765629,0.005685723,0.00006382119,0.00001525943,0.00004969579,0.00004797207,0.0002325035,0.9893913,0.000075521,0.00002933769,0.004252584],"study_design_scores_gemma":[0.000004872959,0.0001406227,0.03078792,0.000006876039,0.00002030564,0.0001528818,0.0001225095,0.002165947,0.9654146,0.0001052494,0.001068334,0.00000995258],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9930592,0.0009404569,0.003849516,0.00003862838,0.0000146441,0.00003091859,0.0004638497,0.00004101622,0.001561814],"genre_scores_gemma":[0.9969215,0.0005729084,0.001335224,0.00002418876,0.000004638368,0.00001718654,0.0003126631,0.00002105773,0.0007906106],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003954224,"threshold_uncertainty_score":0.007862449,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04876177825262831,"score_gpt":0.3458007125927191,"score_spread":0.2970389343400908,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}