{"id":"W3004209596","doi":"10.1021/acs.organomet.9b00836","title":"Rare Carbon-Bridged Bimetallic Lanthanide (Nd or Sm) and Tl(I) Geminal Carbon Derivatives of a Bis(iminophosphorano)methanediide","year":2020,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; University of Alberta","keywords":"Chemistry; Geminal; Bimetallic strip; Lanthanide; Crystallography; Paramagnetism; Ligand (biochemistry); Metal; Crystal structure; Carbon fibers; Medicinal chemistry; Stereochemistry; Ion; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008268973,0.0001884494,0.0002083302,0.0001102206,0.0001118746,0.0002294365,0.0004202893,0.0002240882,0.001009841],"category_scores_gemma":[0.0001497101,0.0001156367,0.0000783517,0.0001338073,0.0001598654,0.0001621741,0.0002699706,0.0002366824,0.0001654168],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004894779,"about_ca_system_score_gemma":0.0001718294,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001176356,"about_ca_topic_score_gemma":0.001679684,"domain_scores_codex":[0.9999287,0.00001305879,0.000005338241,0.00001477734,0.00002014255,0.00001793183],"domain_scores_gemma":[0.999957,0.000005611044,0.00001109565,0.000004540202,0.000007008636,0.00001474914],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006373748,0.00005034803,0.0003625275,0.0001933068,0.000020931,0.0001133865,0.00007711522,0.001243605,0.9926185,0.001078217,0.0002492488,0.003355406],"study_design_scores_gemma":[0.000127337,0.0006368209,0.001100379,0.000009981529,0.00002493937,0.0001260616,0.0000427057,0.005495305,0.9877985,0.00008136046,0.004542412,0.00001417548],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9975068,0.0002051292,0.0006081396,0.00002700076,0.000009572653,0.00001013305,0.00005617036,0.00003226444,0.001544701],"genre_scores_gemma":[0.997526,0.0001308366,0.0009745831,0.00001521726,0.000002643027,0.00001084487,0.0001485309,0.00001201573,0.001179431],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001176356,"threshold_uncertainty_score":0.003551424,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03072107790272878,"score_gpt":0.2272423872048294,"score_spread":0.1965213093021006,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}