{"id":"W3004397739","doi":"10.1021/acs.energyfuels.9b04213","title":"Methyl and Hydrogen Transfer in Free Radical Reactions","year":2020,"lang":"en","type":"article","venue":"Energy & Fuels","topic":"Petroleum Processing and Analysis","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Alberta Innovates; China National Offshore Oil Corporation","keywords":"Intermolecular force; Chemistry; Homolysis; Intramolecular force; Methyl radical; Methyl group; Hydrogen; Photochemistry; Radical; Molecule; Organic chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008290752,0.0005560984,0.0003386989,0.0004633766,0.000646592,0.000579651,0.0008543115,0.001298626,0.005349154],"category_scores_gemma":[0.0009251058,0.000364413,0.0004773497,0.0002425834,0.000943777,0.002579812,0.0008784587,0.001321111,0.0009295634],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005238004,"about_ca_system_score_gemma":0.0002354481,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002167504,"about_ca_topic_score_gemma":0.0002115111,"domain_scores_codex":[0.9993617,0.000133611,0.00002468795,0.0001322692,0.0002100678,0.0001376869],"domain_scores_gemma":[0.9995479,0.0002263273,0.00008184941,0.00005696326,0.00005934851,0.00002759328],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004172911,0.0002167999,0.001693424,0.003302378,0.0001221366,0.001721455,0.0009888406,0.004636331,0.8227999,0.1041634,0.001941416,0.05799673],"study_design_scores_gemma":[0.00004536466,0.0009064249,0.001326747,0.000135959,0.00006187011,0.001106593,0.0002197315,0.006677385,0.9123873,0.02872424,0.04833292,0.00007546259],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7046016,0.1029087,0.1148659,0.002707315,0.002207334,0.0004042301,0.0003598253,0.0004036383,0.07154141],"genre_scores_gemma":[0.9754378,0.007443178,0.006330824,0.0002529885,0.000260081,0.00008034665,0.00009855785,0.00003393757,0.01006214],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005349154,"threshold_uncertainty_score":0.01789474,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01346938406115415,"score_gpt":0.2239085695421485,"score_spread":0.2104391854809943,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}