{"id":"W3006576610","doi":"10.1039/c9sc06224f","title":"<i>In situ</i> monitoring of mechanochemical synthesis of calcium urea phosphate fertilizer cocrystal reveals highly effective water-based autocatalysis","year":2020,"lang":"en","type":"article","venue":"Chemical Science","topic":"Enzyme Structure and Function","field":"Materials Science","cited_by":58,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Division of Chemistry; Deutsches Elektronen-Synchrotron; Natural Sciences and Engineering Research Council of Canada; E.W.R. Steacie Memorial Fund; National Science Foundation","keywords":"Autocatalysis; Cocrystal; Urea; Mechanosynthesis; Chemistry; Calcium; Inorganic chemistry; Chemical engineering; Materials science; Organic chemistry; Catalysis; Molecule; Metallurgy","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009854307,0.0002144806,0.0001415839,0.0001460996,0.0001590954,0.0002137312,0.0003570064,0.0003565237,0.002081885],"category_scores_gemma":[0.0001673984,0.0001085293,0.0001068669,0.0002020013,0.0003625145,0.0002506459,0.0001506136,0.0003729984,0.0001595389],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003062019,"about_ca_system_score_gemma":0.0001242468,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001193859,"about_ca_topic_score_gemma":0.00235892,"domain_scores_codex":[0.9998927,0.000007711093,0.00000551658,0.0000374263,0.00003441677,0.00002218565],"domain_scores_gemma":[0.9999131,0.00002072993,0.00003372687,0.00000836051,0.00001606839,0.000007992368],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006256647,0.00001289781,0.0001811718,0.00005083296,0.000004442053,0.00007771997,0.00002637758,0.00009659538,0.996938,0.0003412946,0.0003320335,0.00187625],"study_design_scores_gemma":[0.00000188654,0.00003124797,0.0008768609,0.000002017287,0.000002155929,0.00005533663,0.0000197807,0.001086262,0.997321,0.00004502399,0.0005545171,0.000003957593],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9784081,0.0007792759,0.009233361,0.0003921989,0.00008227854,0.00002435536,0.001000601,0.0002825027,0.009797324],"genre_scores_gemma":[0.9956288,0.0003000832,0.002556257,0.00007823794,0.00001329968,0.00001759391,0.0002549638,0.00002352934,0.001127156],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002081885,"threshold_uncertainty_score":0.006964564,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01236983496411603,"score_gpt":0.2443611513753953,"score_spread":0.2319913164112793,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}