{"id":"W3009220195","doi":"10.1002/slct.202000122","title":"Synthesis of New Aza‐ and Thia‐Crown Ether Based Amino Acids","year":2020,"lang":"en","type":"article","venue":"ChemistrySelect","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"European Commission","keywords":"Moiety; Crown ether; Amino acid; Heteroatom; Chemistry; Ether; Sulfur; Organic chemistry; Reagent; Combinatorial chemistry; Ion; Biochemistry; Ring (chemistry)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000132185,0.0003346142,0.0004708045,0.00002920956,0.00005365906,0.00003555827,0.0004372871,0.0003296756,0.002654705],"category_scores_gemma":[0.001376385,0.0003386523,0.0001594502,0.0002335469,0.0001641017,0.00005926242,0.0000746029,0.0002999725,0.00001392149],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005683554,"about_ca_system_score_gemma":0.0002408955,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003696542,"about_ca_topic_score_gemma":0.000001257051,"domain_scores_codex":[0.9983985,0.00002028135,0.0003769709,0.0005446489,0.0003082933,0.0003512431],"domain_scores_gemma":[0.9984208,0.0004841479,0.0001937382,0.0005178196,0.00007802078,0.0003055033],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001125316,0.00004706399,0.00310979,0.0005391381,0.00005733619,0.000008178199,0.0001264486,0.000001049576,0.9817487,0.00000714105,0.005142923,0.009099689],"study_design_scores_gemma":[0.0003253592,0.00002189937,0.0001050696,0.0001459379,0.00008788414,0.000006547526,0.00007325347,0.0001741136,0.9939198,0.00006345016,0.004741133,0.0003355828],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9672994,0.0004462157,0.00043918,0.0009747794,0.000009498821,0.00008011636,0.00004432239,0.000511068,0.03019541],"genre_scores_gemma":[0.9943884,0.00002324254,0.00450309,0.0003170283,0.000199928,0.00003525245,0.00001376369,0.00007237118,0.0004469035],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02974851,"threshold_uncertainty_score":0.9999065,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02114387246233507,"score_gpt":0.2395676476287202,"score_spread":0.2184237751663851,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}