{"id":"W3009367547","doi":"10.1039/d0dt00579g","title":"The phosphinoboration of acyl chlorides","year":2020,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor; Mount Allison University; Carleton University; University of Toronto; Toronto Public Health; Sackville Memorial Hospital","funders":"Natural Sciences and Engineering Research Council of Canada; Mount Allison University; University of Toronto; Carleton University","keywords":"Reactivity (psychology); Chemistry; Aryl; Acylation; Medicinal chemistry; Crystallography; Stereochemistry; Organic chemistry; Alkyl; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002471256,0.0004059873,0.0001896496,0.0001295804,0.00018168,0.0002566176,0.0003697419,0.0003514393,0.002468933],"category_scores_gemma":[0.0003931046,0.0001523315,0.0001457117,0.0001339162,0.0002652609,0.0004876777,0.0004452008,0.000372302,0.0005913405],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002048279,"about_ca_system_score_gemma":0.0001785871,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000439665,"about_ca_topic_score_gemma":0.000682793,"domain_scores_codex":[0.9997756,0.0000450299,0.00001442562,0.00004125828,0.000051122,0.00007256795],"domain_scores_gemma":[0.9998977,0.00002428393,0.00002714701,0.00001493829,0.00001964249,0.00001619783],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003154704,0.00001671455,0.0002089211,0.0002006803,0.00001401435,0.0001805427,0.0001489605,0.0002894544,0.9944722,0.0006887077,0.00009894657,0.00336547],"study_design_scores_gemma":[0.00001610822,0.0002526543,0.0002603542,0.000005930554,0.000007298533,0.0001512618,0.00002726312,0.0002408505,0.9967247,0.00007380429,0.002233818,0.000005989336],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9880783,0.001288391,0.002827904,0.0001104881,0.00002818771,0.0000424526,0.0001361966,0.0001023531,0.007385673],"genre_scores_gemma":[0.9958955,0.0005630942,0.0009632414,0.00003899856,0.000005720743,0.00001477891,0.0001156951,0.00002327897,0.002379775],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002468933,"threshold_uncertainty_score":0.008259416,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0154795949629354,"score_gpt":0.2164169233504748,"score_spread":0.2009373283875394,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}