{"id":"W3009865704","doi":"10.1021/acs.jpcc.0c01499","title":"Selenium Substitution Enhances Reverse Intersystem Crossing in a Delayed Fluorescence Emitter","year":2020,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":45,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Engineering and Physical Sciences Research Council; Natural Sciences and Engineering Research Council of Canada","keywords":"Intersystem crossing; Photochemistry; Singlet state; Chemistry; Fluorescence; OLED; Triphenylamine; Atom (system on chip); Atomic physics; Physics; Excited state; Optics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001336375,0.0001840813,0.0001408471,0.00009022807,0.00008034096,0.0002024931,0.000184404,0.0002023429,0.00116718],"category_scores_gemma":[0.0002118167,0.00008952861,0.0001391241,0.00008413272,0.0001184581,0.0001706873,0.0001329939,0.0002939165,0.0002042541],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000179764,"about_ca_system_score_gemma":0.0001326014,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004851669,"about_ca_topic_score_gemma":0.0005401627,"domain_scores_codex":[0.9999337,0.000009918344,0.000006643088,0.00001677565,0.00001728384,0.00001561061],"domain_scores_gemma":[0.9998965,0.00004015398,0.00002410407,0.00001071149,0.00001633336,0.00001223946],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006056897,0.00002419195,0.000152624,0.00001765075,0.000003328683,0.00004979413,0.00001353765,0.0001211283,0.9984138,0.0001184029,0.00001906818,0.001005897],"study_design_scores_gemma":[0.000007630696,0.0001872417,0.0003658744,0.000001529804,0.000004967174,0.00004947764,0.000004834207,0.001002017,0.9980054,0.00001097016,0.0003577404,0.000002192125],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9987948,0.00008370109,0.0005069724,0.00001563628,0.000005112075,0.000004390335,0.00001827028,0.00001593667,0.0005552249],"genre_scores_gemma":[0.9982552,0.0001103845,0.0007961466,0.000009554943,0.000001101686,0.00000315036,0.00003756613,0.000008012438,0.0007788774],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00116718,"threshold_uncertainty_score":0.003904581,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0118521931433852,"score_gpt":0.2441303306546311,"score_spread":0.2322781375112459,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}