{"id":"W3009865704","doi":"10.1021/acs.jpcc.0c01499","title":"Selenium Substitution Enhances Reverse Intersystem Crossing in a Delayed Fluorescence Emitter","year":2020,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":45,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Engineering and Physical Sciences Research Council; Natural Sciences and Engineering Research Council of Canada","keywords":"Intersystem crossing; Photochemistry; Singlet state; Chemistry; Fluorescence; OLED; Triphenylamine; Atom (system on chip); Atomic physics; Physics; Excited state; Optics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002405265,0.0001128853,0.0002027177,0.00001345574,0.00004419236,0.00005634229,0.0003707083,0.00004485465,0.00002171603],"category_scores_gemma":[0.0001208947,0.00007961481,0.00007496895,0.0002383286,0.00009947557,0.0001663087,0.00004648768,0.0006182605,0.00002121738],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001370239,"about_ca_system_score_gemma":0.00005373413,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003647768,"about_ca_topic_score_gemma":3.352964e-7,"domain_scores_codex":[0.9990963,0.0000405799,0.0002883901,0.00007935608,0.0002920974,0.0002033206],"domain_scores_gemma":[0.9995191,0.0001165229,0.00008251196,0.0001165288,0.00006389655,0.0001014414],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005627959,0.00001724848,0.0000462322,0.0001765141,0.0000269878,0.00001876314,0.002514672,0.0005668724,0.9960641,0.000001574792,0.000454362,0.00005636911],"study_design_scores_gemma":[0.0002517015,0.00002752574,0.00003828698,0.0001671903,0.00001594545,0.00003727434,0.0002654569,0.02791939,0.9710014,0.000004696017,0.0001876155,0.00008347622],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9987108,0.0001141587,0.0004516662,0.0003650218,0.00004607269,0.000041839,0.000001748101,0.00002924573,0.0002394524],"genre_scores_gemma":[0.9991785,0.00001234574,0.00007844011,0.00002937417,0.0006684102,7.500651e-7,4.690136e-7,0.00001493322,0.00001677197],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02735252,"threshold_uncertainty_score":0.3246598,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0118521931433852,"score_gpt":0.2441303306546311,"score_spread":0.2322781375112459,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}