{"id":"W3010430644","doi":"10.1021/jacs.0c01283","title":"Ge(0) Compound Stabilized by a Diimino-Carbene Ligand: Synthesis and Ambiphilic Reactivity","year":2020,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":46,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa; Canadian Light Source (Canada); Wilfrid Laurier University; Brock University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Carbene; Chemistry; Reactivity (psychology); Ligand (biochemistry); Adduct; Oxidative addition; Moiety; Cycloaddition; Germanium; Pyridine; Medicinal chemistry; Stereochemistry; Chalcogen; Organometallic chemistry; Crystal structure; Photochemistry; Crystallography; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006639626,0.0002368323,0.0001193559,0.0001367895,0.0001025734,0.0002219505,0.0002176301,0.0002136087,0.001184184],"category_scores_gemma":[0.00006786551,0.00009827674,0.00005943239,0.00009557728,0.0001345533,0.00009792519,0.0001748068,0.0001379615,0.0002837851],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002618076,"about_ca_system_score_gemma":0.00009524619,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005641411,"about_ca_topic_score_gemma":0.00112226,"domain_scores_codex":[0.9999548,0.00000536225,0.000002549325,0.00001244883,0.000009163485,0.00001574079],"domain_scores_gemma":[0.9999774,0.000002883819,0.000004734122,0.000002515424,0.000003373269,0.000009143682],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000512378,0.000009529839,0.0000875499,0.00003704943,0.000003690628,0.00008124764,0.00001885737,0.00008885247,0.9979804,0.0003610557,0.0000657463,0.001214741],"study_design_scores_gemma":[0.00001288327,0.0002029073,0.0008258178,0.000004055134,0.000006385379,0.0001463693,0.00001208035,0.0003315086,0.9954333,0.00002652546,0.002992182,0.000005992847],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.991654,0.0007544314,0.002035166,0.0000443977,0.00001223984,0.00003189529,0.0002245474,0.00008913669,0.005154137],"genre_scores_gemma":[0.9956726,0.0002328774,0.001923256,0.00001669198,0.000002561016,0.00001286528,0.0001650444,0.00001289825,0.001961176],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001184184,"threshold_uncertainty_score":0.003961504,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01578500077701676,"score_gpt":0.2245791277340315,"score_spread":0.2087941269570147,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}