{"id":"W3011755375","doi":"10.1515/znb-2019-0212","title":"Transition metal complexes of monodentate 2-oxazolines containing long chain alkyl groups. The crystal structure of <i>trans</i>-PdCl<sub>2</sub>(<i>κ</i> <sup>1</sup>-<i>N</i>-<i>rac</i>-2-heptadecyl-4,5-dihydro-5-methyl-2-oxazole)<sub>2</sub>","year":2020,"lang":"en","type":"article","venue":"Zeitschrift für Naturforschung B","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Western University; Toronto Metropolitan University; Xerox (Canada)","funders":"","keywords":"Chemistry; Denticity; Alkyl; Ligand (biochemistry); Bromobenzene; Oxazoline; Transition metal; Stereochemistry; Crystal structure; Crystallography; Palladium; Metal; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.001248219,0.001386601,0.002835169,0.0004501986,0.0005788411,0.0001460436,0.001067973,0.0006962501,0.0001428544],"category_scores_gemma":[0.0004691183,0.001032103,0.001427076,0.001435473,0.0009466209,0.0008416986,0.0002897744,0.002126509,0.00002125714],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000364628,"about_ca_system_score_gemma":0.0003145696,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001291911,"about_ca_topic_score_gemma":0.00007726713,"domain_scores_codex":[0.9917922,0.0007795672,0.002622552,0.001411918,0.002018994,0.001374763],"domain_scores_gemma":[0.9955422,0.0007543368,0.001135741,0.001175173,0.0007182715,0.0006742271],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.003509303,0.0002691045,0.00093275,0.001566967,0.001142482,0.00007594236,0.005979414,0.003573321,0.9780446,0.001127101,0.0003578138,0.00342124],"study_design_scores_gemma":[0.004063328,0.001321214,0.001721208,0.0006988087,0.001568745,0.0002996474,0.001964879,0.01213138,0.9719251,0.0001718632,0.003100565,0.001033219],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9824719,0.008336293,0.002290236,0.002693086,0.000407128,0.00215621,0.0008980382,0.0003035076,0.0004436294],"genre_scores_gemma":[0.9934229,0.0009514728,0.001005796,0.002791227,0.0008725407,0.00006190519,0.0005946059,0.0002848516,0.00001471281],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01095102,"threshold_uncertainty_score":0.9998884,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01863655799358087,"score_gpt":0.2443455969277489,"score_spread":0.225709038934168,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}