{"id":"W3012128437","doi":"10.1002/anie.202002861","title":"Selective Enzymatic Oxidation of Silanes to Silanols","year":2020,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Enzyme-mediated dye degradation","field":"Agricultural and Biological Sciences","cited_by":78,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dow Chemical (Canada)","funders":"Deutsche Forschungsgemeinschaft; Dow Chemical Company; National Institute of General Medical Sciences; Joan Rothenberg Family Foundation","keywords":"Silanes; Chemistry; Organic chemistry; Enzyme; Silane","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007905889,0.00009046079,0.0001071731,0.00001850919,0.00003540868,0.00002557509,0.0001727825,0.00006409477,0.0004846308],"category_scores_gemma":[0.0003705787,0.0000466549,0.00004844202,0.0002887947,0.00001712426,0.0002254945,0.00003217507,0.00006779072,0.00008276324],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000417893,"about_ca_system_score_gemma":0.000007407323,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005418159,"about_ca_topic_score_gemma":0.00004812958,"domain_scores_codex":[0.9991351,0.00001816425,0.0002182558,0.0001942968,0.0003338216,0.000100302],"domain_scores_gemma":[0.9993811,0.0001261663,0.0001307942,0.00002633499,0.0002528699,0.00008274812],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000396638,0.00003395818,0.0008910943,0.000006695417,0.00001664793,7.223085e-7,0.0002200713,0.00001615095,0.9833052,0.0001140278,0.01343099,0.001924741],"study_design_scores_gemma":[0.0001159757,0.0001208942,0.01762607,0.00002461184,0.00000628179,0.00000133573,0.0001458911,0.00007925688,0.9760974,0.0002849567,0.005404663,0.00009267452],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9864355,0.00001965294,0.0004880097,0.009822206,0.0002987696,0.0001972964,0.0001477735,0.00007663322,0.002514201],"genre_scores_gemma":[0.9960476,0.00001824096,0.0001959174,0.0009966537,0.001147506,0.00002747844,0.001509477,0.00000120927,0.00005592269],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01673497,"threshold_uncertainty_score":0.5306367,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02172077525250505,"score_gpt":0.2315086146336821,"score_spread":0.209787839381177,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}