{"id":"W3013383340","doi":"10.1002/cssc.201902576","title":"Catalytic Room‐Temperature C−N Coupling of Amides and Isocyanates by Using Mechanochemistry","year":2020,"lang":"en","type":"article","venue":"ChemSusChem","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Natural Sciences and Engineering Research Council of Canada; McGill University; International Centre for Diffraction Data","keywords":"Mechanochemistry; Catalysis; Coupling (piping); Chemistry; Heterogeneous catalysis; Chemical engineering; Materials science; Organic chemistry; Composite material","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002116354,0.0004839883,0.0002113789,0.0001724507,0.0001372554,0.000205297,0.0003052511,0.0003037384,0.0008457973],"category_scores_gemma":[0.0001547021,0.0002069323,0.0002277962,0.0001172393,0.0004074146,0.0002473324,0.0003266222,0.0004053851,0.0003934212],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002959289,"about_ca_system_score_gemma":0.0002795577,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003305533,"about_ca_topic_score_gemma":0.0008104398,"domain_scores_codex":[0.999846,0.00001420763,0.00000673844,0.00004642855,0.00004732148,0.00003927034],"domain_scores_gemma":[0.9999139,0.00001575362,0.00003249698,0.00001243375,0.00001228107,0.00001299651],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001131709,0.00001006539,0.00004636071,0.000049528,0.000002622483,0.00005749915,0.00001367727,0.00007757194,0.9962954,0.0005274733,0.00004710264,0.002861471],"study_design_scores_gemma":[0.000005436379,0.00009397669,0.0004489616,0.000004851076,0.000003034044,0.0001720137,0.000008053664,0.0006203533,0.9959837,0.00007588527,0.0025763,0.000007380998],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9072296,0.003434007,0.07211977,0.0001881118,0.0001698151,0.0001970543,0.0001318619,0.0004060421,0.01612363],"genre_scores_gemma":[0.9714267,0.00166217,0.02293552,0.00007396795,0.00003074241,0.0001060157,0.0001167516,0.00004279426,0.003605431],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008457973,"threshold_uncertainty_score":0.002829432,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009412119146818379,"score_gpt":0.2184269000916925,"score_spread":0.2090147809448742,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}