{"id":"W3013862396","doi":"10.1039/d0ee00342e","title":"Determining the limiting factor of the electrochemical stability window for PEO-based solid polymer electrolytes: main chain or terminal –OH group?","year":2020,"lang":"en","type":"article","venue":"Energy & Environmental Science","topic":"Advanced Battery Materials and Technologies","field":"Engineering","cited_by":662,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Toronto Public Health; Western University","funders":"Natural Sciences and Engineering Research Council of Canada; Mitacs; Canada Research Chairs; Ontario Research Foundation; Western University; Compute Canada; University of Toronto","keywords":"Electrolyte; Terminal (telecommunication); Electrochemistry; Limiting; Polymer; Electrochemical window; Materials science; Solid-state; Chemical engineering; Window (computing); Side chain; Polymer chemistry; Electrode; Chemistry; Computer science; Ionic conductivity; Composite material; Telecommunications; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001056019,0.0007574478,0.0004809338,0.0003421315,0.0002476349,0.0007830477,0.0005555398,0.001012974,0.002882459],"category_scores_gemma":[0.004024072,0.0003101527,0.0002721707,0.0002019849,0.0004869955,0.003027962,0.0003119031,0.0009889849,0.001459578],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003765515,"about_ca_system_score_gemma":0.0003373393,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006947976,"about_ca_topic_score_gemma":0.0005831512,"domain_scores_codex":[0.9995325,0.0000637299,0.00003747831,0.000161419,0.0001385019,0.00006636753],"domain_scores_gemma":[0.9986368,0.000726517,0.0002088563,0.00006854038,0.0002794633,0.00007978638],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003681733,0.0001006992,0.002190148,0.0005539978,0.0000229391,0.0002278524,0.0001229127,0.0004327165,0.9684405,0.001994381,0.000641241,0.02490453],"study_design_scores_gemma":[0.00001236919,0.0001595606,0.001197226,0.0000501115,0.00002986521,0.0002468487,0.00006702878,0.004009968,0.9880607,0.000886544,0.005255539,0.00002418657],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8562098,0.02615158,0.1040169,0.002321263,0.0004821936,0.0002238342,0.0008802762,0.0006567182,0.009057532],"genre_scores_gemma":[0.9734211,0.006894364,0.01591596,0.0003568945,0.0001210219,0.0001372827,0.0004171644,0.0000859013,0.002650384],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002882459,"threshold_uncertainty_score":0.00964278,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01162147648794426,"score_gpt":0.1995693280214612,"score_spread":0.187947851533517,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}