{"id":"W3013954099","doi":"10.1021/acsomega.0c00479","title":"Dibenzo[<i>f,h</i>]furazano[3,4-<i>b</i>]quinoxalines: Synthesis by Intramolecular Cyclization through Direct Transition Metal-Free C–H Functionalization and Electrochemical, Photophysical, and Charge Mobility Characterization","year":2020,"lang":"en","type":"article","venue":"ACS Omega","topic":"Organic Electronics and Photovoltaics","field":"Engineering","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Russian Science Foundation; Russian Foundation for Basic Research","keywords":"Surface modification; Intramolecular force; Electrochemistry; Transition metal; Electron mobility; Materials science; HOMO/LUMO; Chemistry; Photochemistry; Stereochemistry; Physical chemistry; Electrode; Organic chemistry; Catalysis; Optoelectronics; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006807449,0.0002373857,0.00007376396,0.000152444,0.00009783372,0.0001539816,0.0001674524,0.0001406711,0.002718282],"category_scores_gemma":[0.00005840539,0.00009713096,0.00006004707,0.00009041652,0.000107444,0.0001630062,0.00006303108,0.0001998164,0.0004615025],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000168919,"about_ca_system_score_gemma":0.00008359068,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003245098,"about_ca_topic_score_gemma":0.0007652088,"domain_scores_codex":[0.9999585,0.000003864272,0.000002039621,0.00001415644,0.00001113664,0.00001037132],"domain_scores_gemma":[0.9999627,0.000006596688,0.00001214741,0.000003890655,0.000006924011,0.000007737593],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000156248,0.000005435719,0.00004540997,0.00001088659,8.130908e-7,0.0000123519,0.000005612709,0.00001734701,0.9986752,0.00007093366,0.00004007202,0.001100333],"study_design_scores_gemma":[0.00000352023,0.0000599035,0.0009066474,8.802062e-7,0.000001841048,0.00006029433,0.000006457829,0.0002523316,0.9971297,0.00002441786,0.001551714,0.000002278857],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9664828,0.00111919,0.02476885,0.0001512787,0.00003001565,0.0000600271,0.000892296,0.0002731353,0.006222328],"genre_scores_gemma":[0.9737024,0.0007154464,0.01818623,0.00004613933,0.00001155689,0.00006663334,0.0008871939,0.00003872167,0.006345504],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002718282,"threshold_uncertainty_score":0.009093523,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005356425269137654,"score_gpt":0.1768508184873995,"score_spread":0.1714943932182618,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}