{"id":"W3013954099","doi":"10.1021/acsomega.0c00479","title":"Dibenzo[<i>f,h</i>]furazano[3,4-<i>b</i>]quinoxalines: Synthesis by Intramolecular Cyclization through Direct Transition Metal-Free C–H Functionalization and Electrochemical, Photophysical, and Charge Mobility Characterization","year":2020,"lang":"en","type":"article","venue":"ACS Omega","topic":"Organic Electronics and Photovoltaics","field":"Engineering","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Russian Science Foundation; Russian Foundation for Basic Research","keywords":"Surface modification; Intramolecular force; Electrochemistry; Transition metal; Electron mobility; Materials science; HOMO/LUMO; Chemistry; Photochemistry; Stereochemistry; Physical chemistry; Electrode; Organic chemistry; Catalysis; Optoelectronics; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.00008646529,0.0002795028,0.0003101375,0.00003261544,0.0001222826,0.00008864337,0.0001144224,0.0001566907,0.00002265357],"category_scores_gemma":[0.0001112101,0.0003007897,0.00004861926,0.0004265567,0.00005700302,0.0004473439,0.0000314493,0.0001821501,0.000004697737],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000533909,"about_ca_system_score_gemma":0.00001955422,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008913215,"about_ca_topic_score_gemma":0.000002232888,"domain_scores_codex":[0.998711,0.00004889083,0.0003130936,0.0004161113,0.0002225926,0.0002883355],"domain_scores_gemma":[0.9994588,0.0000738927,0.00006340245,0.0002180399,0.00006777717,0.0001180825],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002914155,0.00005591324,0.00003487756,0.0001575275,0.00007358786,6.529262e-7,0.0003513386,0.00003599477,0.9982176,0.0002984277,0.0004796805,0.0002652584],"study_design_scores_gemma":[0.000372083,0.00009013998,0.00009573712,0.00001964868,0.0001176132,0.000003700911,0.0000136622,0.01600337,0.9772781,0.000485471,0.005194458,0.000325987],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9632299,0.001127027,0.03389641,0.0006551371,0.00006515443,0.0003831967,0.0001641395,0.0003362914,0.0001427636],"genre_scores_gemma":[0.99576,0.002376562,0.00009645892,0.0007141581,0.0001337051,0.0000754932,0.000767376,0.00006839919,0.000007866613],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03379995,"threshold_uncertainty_score":0.9999444,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005356425269137654,"score_gpt":0.1768508184873995,"score_spread":0.1714943932182618,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}