{"id":"W3014561922","doi":"10.1002/cnma.202000158","title":"Enhancing Galvanic Replacement in Plasmonic Hollow Nanoparticles: Understanding the Role of the Speciation of Metal Ion Precursors","year":2020,"lang":"en","type":"article","venue":"ChemNanoMat","topic":"Gold and Silver Nanoparticles Synthesis and Applications","field":"Materials Science","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Plasmon; Materials science; Galvanic cell; Nanostructure; Nanoparticle; Surface plasmon resonance; Metal; Nanotechnology; Nanoscopic scale; Porosity; Ligand (biochemistry); Metal ions in aqueous solution; Chemical engineering; Chemistry; Optoelectronics; Metallurgy; Composite material","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002647659,0.000235826,0.0002208745,0.00008129342,0.00008006311,0.0003602739,0.0002906406,0.0003405613,0.0002865264],"category_scores_gemma":[0.0002505491,0.000163234,0.0001443909,0.00005657676,0.0003773912,0.0004713305,0.0001566577,0.0002789321,0.0001185051],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004049931,"about_ca_system_score_gemma":0.0001488999,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005094143,"about_ca_topic_score_gemma":0.0005631359,"domain_scores_codex":[0.999915,0.00001595879,0.000006126535,0.00002674162,0.00002097897,0.00001517608],"domain_scores_gemma":[0.9999205,0.00003699193,0.00001865963,0.000006452028,0.00001181632,0.000005578931],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001825129,0.000008284188,0.00006156024,0.00004881813,0.000001803435,0.00001647796,0.00002013854,0.0003415374,0.9979522,0.0002466405,0.00001411777,0.001270306],"study_design_scores_gemma":[0.000002434954,0.00002381427,0.0001492091,0.000001906431,0.000002423213,0.0000198195,0.000008091363,0.004517871,0.9948436,0.00008148377,0.000347019,0.000002367272],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9744383,0.002052286,0.02159368,0.0002174395,0.0000218099,0.00003049217,0.0000441868,0.0001333151,0.001468473],"genre_scores_gemma":[0.9910398,0.0008103288,0.00758856,0.00004593418,0.000005594306,0.0000123076,0.0000248886,0.00001498361,0.0004576057],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005094143,"threshold_uncertainty_score":0.002938509,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02367314631398101,"score_gpt":0.2181414045622939,"score_spread":0.1944682582483128,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}