{"id":"W3014620201","doi":"10.1039/d0dt00285b","title":"Bulky bis(aryl)triazenides: just aspiring amidinates? A structural and spectroscopic study","year":2020,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Chemical Reactions and Mechanisms","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Kensington Health","funders":"Australian Research Council","keywords":"Chemistry; Disproportionation; Ligand (biochemistry); Steric effects; Aryl; Lability; Hydride; Infrared spectroscopy; Crystallography; Nuclear magnetic resonance spectroscopy; Coordination complex; Lewis acids and bases; Metal; Halide; Stereochemistry; Alkyl; Inorganic chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001173484,0.000168137,0.0001480653,0.0001009373,0.0001031754,0.0002039945,0.0002827586,0.0002435224,0.001759147],"category_scores_gemma":[0.0001223319,0.00009927042,0.00008265417,0.0001306513,0.0002075808,0.0002756584,0.0001236814,0.0002835288,0.0003198482],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001401443,"about_ca_system_score_gemma":0.00005422878,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003398816,"about_ca_topic_score_gemma":0.0004276013,"domain_scores_codex":[0.9999515,0.00001106581,0.000002145016,0.000009176335,0.00001392362,0.00001219906],"domain_scores_gemma":[0.9999651,0.000009925062,0.000010652,0.000005071856,0.00000493475,0.000004431158],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000496291,0.00002725654,0.0001247454,0.0001277562,0.000008653603,0.0001616124,0.00007759034,0.0002491779,0.9889256,0.002373444,0.0002590929,0.007168752],"study_design_scores_gemma":[0.00006754816,0.001349728,0.001439425,0.00001628394,0.00002841437,0.0004864555,0.0001417757,0.001439951,0.9819994,0.0007488017,0.01226861,0.00001357339],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9830322,0.00448083,0.003254734,0.0002503036,0.00003236648,0.0000178129,0.00009756425,0.00007587725,0.008758298],"genre_scores_gemma":[0.9934725,0.002516107,0.001079754,0.00007371271,0.00001448015,0.000007560847,0.00009810527,0.00001208498,0.002725748],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001759147,"threshold_uncertainty_score":0.005884886,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02806902772191972,"score_gpt":0.2737222631771627,"score_spread":0.245653235455243,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}