{"id":"W3014741696","doi":"10.1021/acscatal.0c00988","title":"Catalytic Alkyne Dimerization without Noble Metals","year":2020,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":67,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; Government of Ontario","keywords":"Alkyne; Synthon; Catalysis; Noble metal; Chemistry; Combinatorial chemistry; Atom economy; Nanotechnology; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001629715,0.0004360326,0.0002352726,0.0001278719,0.0001386414,0.0002586288,0.0003791477,0.0003799358,0.00167658],"category_scores_gemma":[0.0002339814,0.000203879,0.0001578566,0.0001690325,0.0001785116,0.0005755696,0.0004341388,0.0007367216,0.001063689],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002882352,"about_ca_system_score_gemma":0.0001529288,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002511748,"about_ca_topic_score_gemma":0.0005196443,"domain_scores_codex":[0.9998172,0.00001899313,0.00001172924,0.00006881604,0.00004723521,0.00003618584],"domain_scores_gemma":[0.9999663,0.00000881363,0.000007929903,0.000005013251,0.00000584643,0.000006061998],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009259021,0.00005909305,0.0001242717,0.000929697,0.00003165579,0.0002436349,0.0001412311,0.0005860169,0.9576213,0.009201439,0.003979717,0.02698938],"study_design_scores_gemma":[0.00001985456,0.0001316729,0.0002459025,0.00002597133,0.00001440458,0.0004200392,0.00003133998,0.002907385,0.9266916,0.000736957,0.0687555,0.00001933104],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7057588,0.08608431,0.1040215,0.002258787,0.001908252,0.0002180231,0.0009447297,0.001352992,0.09745263],"genre_scores_gemma":[0.952995,0.0215352,0.0121923,0.000429817,0.0001538824,0.00005512618,0.0003660247,0.00006416546,0.01220846],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00167658,"threshold_uncertainty_score":0.005608737,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03016916438238881,"score_gpt":0.2796603375033688,"score_spread":0.24949117312098,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}