{"id":"W3014955896","doi":"10.1063/5.0003886","title":"High-temperature hypersonic Laval nozzle for non-LTE cavity ringdown spectroscopy","year":2020,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Spectroscopy and Laser Applications","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Institut national des sciences de l'Univers; Indo-French Centre for the Promotion of Advanced Research; Agence Nationale de la Recherche","keywords":"Vibrational temperature; Nozzle; Rotational temperature; Population; Vibrational energy relaxation; Atomic physics; Chemistry; Spectroscopy; Materials science; Physics; Molecule; Excited state; Thermodynamics","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004901803,0.0003637347,0.0004718376,0.0001964162,0.0002950997,0.000311466,0.000718014,0.0004934384,0.00223042],"category_scores_gemma":[0.0006066927,0.0001632445,0.0002257127,0.0001991888,0.0002918229,0.0003215362,0.0005327475,0.0005260397,0.0005661899],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004876384,"about_ca_system_score_gemma":0.0003696493,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004332575,"about_ca_topic_score_gemma":0.0004029361,"domain_scores_codex":[0.9996275,0.00004485523,0.00001253883,0.00008398589,0.0001789762,0.00005214295],"domain_scores_gemma":[0.9996462,0.0001114804,0.00005028559,0.00007520551,0.00008470287,0.00003212415],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001481897,0.00002664098,0.0007911585,0.00009219984,0.000003305186,0.00006941897,0.00005526393,0.0009894505,0.9894214,0.001260825,0.0004777705,0.006664526],"study_design_scores_gemma":[0.00004968421,0.0003292832,0.005551731,0.00001226252,0.000006486346,0.0001938816,0.00002505449,0.03964554,0.9459336,0.0001815758,0.008035654,0.0000352035],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.832001,0.0007000577,0.1583401,0.0001104754,0.0001307353,0.0003975364,0.001902622,0.001823865,0.004593646],"genre_scores_gemma":[0.8733207,0.0001508439,0.122886,0.00004359119,0.00002286725,0.0003807954,0.001112598,0.0001547238,0.001927801],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00223042,"threshold_uncertainty_score":0.007461429,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01130491881703357,"score_gpt":0.2521584757987551,"score_spread":0.2408535569817215,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}