{"id":"W3014996300","doi":"10.1021/acs.organomet.0c00058","title":"Synthesis of Pyridines, Quinolines, and Pyrimidines via Acceptorless Dehydrogenative Coupling Catalyzed by a Simple Bidentate <i>P</i>^<i>N</i> Ligand Supported Ru Complex","year":2020,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":57,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation","keywords":"Chemistry; Ruthenium; Ligand (biochemistry); Denticity; Protonation; Catalysis; Aldehyde; Reactivity (psychology); Adduct; Combinatorial chemistry; Phenanthridine; Medicinal chemistry; Stereochemistry; Metal; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001786631,0.0004264599,0.0008338281,0.0001829721,0.0001548062,0.00007404406,0.0004720271,0.0001711364,0.001491214],"category_scores_gemma":[0.000390763,0.0004236468,0.0001958816,0.001504012,0.0002160562,0.0002440398,0.000262384,0.0001771617,0.0000368879],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006366624,"about_ca_system_score_gemma":0.0000848968,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001542596,"about_ca_topic_score_gemma":0.00002086234,"domain_scores_codex":[0.9975968,0.00002007205,0.0008109848,0.0006341894,0.0005032047,0.0004347264],"domain_scores_gemma":[0.9981998,0.0002551629,0.0005249195,0.0003711767,0.0002332864,0.0004157082],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005309084,0.0001523662,0.004401412,0.0003075367,0.0004767107,0.00001046418,0.0004982249,0.00007087357,0.9901348,0.00002294351,0.001085235,0.002786294],"study_design_scores_gemma":[0.0007396627,0.00001635771,0.0001061194,0.0000136684,0.000385415,0.00001075562,0.000614998,0.01242648,0.9788874,0.00002684544,0.006324351,0.0004479939],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9956667,0.001081144,0.001162398,0.0005175491,0.00002641537,0.0001529917,0.0007327253,0.0001659895,0.0004940683],"genre_scores_gemma":[0.9973817,0.0006041354,0.0001627533,0.0002661192,0.0000982627,0.00002997703,0.001269556,0.00009262814,0.00009484518],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0123556,"threshold_uncertainty_score":0.9998215,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02060475679216495,"score_gpt":0.2395511109557336,"score_spread":0.2189463541635686,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}