{"id":"W3014996300","doi":"10.1021/acs.organomet.0c00058","title":"Synthesis of Pyridines, Quinolines, and Pyrimidines via Acceptorless Dehydrogenative Coupling Catalyzed by a Simple Bidentate <i>P</i>^<i>N</i> Ligand Supported Ru Complex","year":2020,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":57,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation","keywords":"Chemistry; Ruthenium; Ligand (biochemistry); Denticity; Protonation; Catalysis; Aldehyde; Reactivity (psychology); Adduct; Combinatorial chemistry; Phenanthridine; Medicinal chemistry; Stereochemistry; Metal; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000179432,0.0003996605,0.0002757001,0.0001624164,0.0002001762,0.0001916815,0.0006159783,0.0002838352,0.0009720507],"category_scores_gemma":[0.0001753723,0.0002067826,0.0001780065,0.0001722349,0.0001709124,0.0003573438,0.00032357,0.0004841046,0.0004586212],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003299693,"about_ca_system_score_gemma":0.0002982123,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004325952,"about_ca_topic_score_gemma":0.001215058,"domain_scores_codex":[0.9998766,0.0000139114,0.0000117914,0.00003634993,0.00003254008,0.00002871526],"domain_scores_gemma":[0.999935,0.000009749998,0.00001507144,0.00001440058,0.00000807067,0.00001773275],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000828941,0.00006974288,0.0002416152,0.0002764009,0.00002121131,0.0003474437,0.0001352609,0.0004972618,0.9831686,0.002256657,0.0002102629,0.01269256],"study_design_scores_gemma":[0.00002299048,0.0004876864,0.000616394,0.000007154374,0.00001820537,0.0003663658,0.00002513888,0.0009665727,0.9896355,0.0001662586,0.007670602,0.00001719855],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9585059,0.003388863,0.02304028,0.0002019126,0.0001030506,0.0001233834,0.000467538,0.0002894713,0.01387952],"genre_scores_gemma":[0.990361,0.001070209,0.006275357,0.00002344626,0.000008866516,0.00001952527,0.000164004,0.00001796258,0.002059674],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009720507,"threshold_uncertainty_score":0.003251851,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02060475679216495,"score_gpt":0.2395511109557336,"score_spread":0.2189463541635686,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}