{"id":"W3015120794","doi":"10.1039/d0sc00712a","title":"Recent advances in photoredox and nickel dual-catalyzed cascade reactions: pushing the boundaries of complexity","year":2020,"lang":"en","type":"review","venue":"Chemical Science","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":354,"is_retracted":false,"has_abstract":true,"ca_institutions":"Kootenay Association for Science & Technology","funders":"King Abdullah University of Science and Technology","keywords":"Cascade; Dual (grammatical number); Catalysis; Nickel; Combinatorial chemistry; Computer science; Chemistry; Organic chemistry; Philosophy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007648505,0.0009783132,0.0009469808,0.001719815,0.0002382774,0.0008989897,0.0007404845,0.000869439,0.003067566],"category_scores_gemma":[0.000712864,0.0004322393,0.0004515744,0.002059935,0.0004864467,0.001601778,0.0007153794,0.001880599,0.00151307],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005947389,"about_ca_system_score_gemma":0.0008932452,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007175246,"about_ca_topic_score_gemma":0.001510124,"domain_scores_codex":[0.9998246,0.00002216493,0.00001860858,0.00003780618,0.00006898193,0.0000278679],"domain_scores_gemma":[0.9997141,0.0001396994,0.00004124331,0.00001065323,0.0000622737,0.00003204072],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00009382499,0.0001147615,0.0002076382,0.02831079,0.0001072852,0.0002990229,0.0001165995,0.0008327006,0.00976186,0.01681479,0.02510789,0.918233],"study_design_scores_gemma":[0.00001497732,0.0001041917,0.0003164471,0.000974085,0.00007467943,0.0005693056,0.00004211412,0.00012842,0.002254843,0.002156875,0.9933438,0.00002024067],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.0003297717,0.9967514,0.0003976164,0.0001914243,0.0002026355,0.000006015095,0.00001755345,0.00001339483,0.00209012],"genre_scores_gemma":[0.001665597,0.9966238,0.0004226291,0.0002135274,0.0001332163,0.00000911786,0.00003438449,0.000002566949,0.0008951696],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.003067566,"threshold_uncertainty_score":0.01026201,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05862964903323364,"score_gpt":0.3488170732206569,"score_spread":0.2901874241874233,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}