{"id":"W3015547715","doi":"10.3390/molecules25071692","title":"Push–Pull Zinc Phthalocyanine Bearing Hexa-Tertiary Substituted Carbazolyl Donor Groups for Dye-Sensitized Solar Cells","year":2020,"lang":"en","type":"article","venue":"Molecules","topic":"TiO2 Photocatalysis and Solar Cells","field":"Energy","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Campus France; European Commission; Agence Nationale de la Recherche; Ottawa Hospital Research Institute","keywords":"Photosensitizer; Phthalocyanine; Photochemistry; Dye-sensitized solar cell; Delocalized electron; Chemistry; HOMO/LUMO; HEXA; Zinc; Molecule; Organic chemistry; Crystallography; Physical chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001493054,0.0003504825,0.0002965135,0.0001482289,0.0001397858,0.0002659748,0.0003259112,0.0002983169,0.0009755215],"category_scores_gemma":[0.0001494755,0.0001575952,0.0001714566,0.0002272716,0.0001763119,0.0003464395,0.0001913696,0.000487772,0.0004292386],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000320189,"about_ca_system_score_gemma":0.0001951932,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003361428,"about_ca_topic_score_gemma":0.0008059457,"domain_scores_codex":[0.9998963,0.00001256403,0.000008643823,0.00002319123,0.00003587128,0.00002339058],"domain_scores_gemma":[0.9998957,0.00001601984,0.00002958466,0.00001913958,0.00001638608,0.00002327745],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002313632,0.000009077634,0.00004030422,0.00004165637,0.000001585746,0.00002851789,0.000005461225,0.00007484651,0.9988453,0.00007133776,0.00001789984,0.0008408565],"study_design_scores_gemma":[0.000007874027,0.00007729912,0.0002787596,0.00000143729,0.000004540886,0.00006321425,0.000003787187,0.0004679343,0.9984085,0.00001303623,0.000670681,0.000002952814],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9857484,0.001368036,0.01053975,0.0001256661,0.00004053214,0.00008935232,0.0003276355,0.0001874223,0.001573195],"genre_scores_gemma":[0.9904612,0.0006529902,0.007028359,0.00002705142,0.00000888791,0.00003900676,0.0001456101,0.00003100218,0.001605974],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009755215,"threshold_uncertainty_score":0.003263414,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01723273060981342,"score_gpt":0.2161329907167838,"score_spread":0.1989002601069703,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}