{"id":"W3015654136","doi":"10.1002/pca.2935","title":"Rapid structural characterisation of benzylisoquinoline and aporphine alkaloids from <i>Ocotea spixiana</i> acaricide extract by HPTLC‐DESI‐MS<sup><i>n</i></sup>","year":2020,"lang":"en","type":"article","venue":"Phytochemical Analysis","topic":"Traditional and Medicinal Uses of Annonaceae","field":"Biochemistry, Genetics and Molecular Biology","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"Fundação de Amparo à Pesquisa do Estado da Bahia; Conselho Nacional de Desenvolvimento Científico e Tecnológico; Coordenação de Aperfeiçoamento de Pessoal de Nível Superior","keywords":"Chemistry; Benzylisoquinoline; Aporphine; Chromatography; Alkaloid; Corydalis; Acaricide; Lauraceae; Palmatine; Stereochemistry; Organic chemistry; Botany","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009389585,0.0004724658,0.0001845537,0.0004532269,0.0001644443,0.0002211757,0.0001480251,0.0002115908,0.001004852],"category_scores_gemma":[0.0002008848,0.00009359245,0.0003013185,0.0002383482,0.0002209579,0.0002869471,0.0001427766,0.0003343121,0.0002617622],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000140501,"about_ca_system_score_gemma":0.000219976,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001235846,"about_ca_topic_score_gemma":0.001245993,"domain_scores_codex":[0.9999329,0.000006356137,0.000004869656,0.00001842712,0.00002817754,0.000009350021],"domain_scores_gemma":[0.9998615,0.0000299814,0.00003681105,0.00001283515,0.0000446305,0.00001424687],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006464585,0.00001057381,0.0004162664,0.00005687881,0.000005950825,0.00005735657,0.00002076896,0.00003735365,0.9965821,0.00002307742,0.00001405398,0.00271102],"study_design_scores_gemma":[0.0000179852,0.0006114229,0.03992388,0.00002194599,0.00004318656,0.0006720183,0.00009417101,0.0009818915,0.9544169,0.00006611688,0.003135113,0.00001530404],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9891839,0.001667062,0.005069233,0.00004573544,0.00001412964,0.00006555268,0.0009157213,0.00007640394,0.002962209],"genre_scores_gemma":[0.9885536,0.001227652,0.006335992,0.00007930073,0.00001723796,0.00005755715,0.001501324,0.00004261974,0.002184777],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001235846,"threshold_uncertainty_score":0.003361523,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01051705393605013,"score_gpt":0.220479444938514,"score_spread":0.2099623910024638,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}