{"id":"W3015654136","doi":"10.1002/pca.2935","title":"Rapid structural characterisation of benzylisoquinoline and aporphine alkaloids from <i>Ocotea spixiana</i> acaricide extract by HPTLC‐DESI‐MS<sup><i>n</i></sup>","year":2020,"lang":"en","type":"article","venue":"Phytochemical Analysis","topic":"Traditional and Medicinal Uses of Annonaceae","field":"Biochemistry, Genetics and Molecular Biology","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"Fundação de Amparo à Pesquisa do Estado da Bahia; Conselho Nacional de Desenvolvimento Científico e Tecnológico; Coordenação de Aperfeiçoamento de Pessoal de Nível Superior","keywords":"Chemistry; Benzylisoquinoline; Aporphine; Chromatography; Alkaloid; Corydalis; Acaricide; Lauraceae; Palmatine; Stereochemistry; Organic chemistry; Botany","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006697897,0.0002650824,0.0004972753,0.00005708974,0.00005110394,0.00001848608,0.0002168536,0.0001801955,0.0002386822],"category_scores_gemma":[0.00009201683,0.0002365148,0.0002895686,0.00034493,0.0001654438,0.00001877317,0.00009013105,0.0001836286,0.000003884326],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001090361,"about_ca_system_score_gemma":0.00002839603,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001535145,"about_ca_topic_score_gemma":0.000005731957,"domain_scores_codex":[0.9984199,0.00003661324,0.0004476177,0.0005635084,0.0002912563,0.0002410451],"domain_scores_gemma":[0.9991225,0.0000382184,0.0002033217,0.0002430752,0.0001061994,0.0002867099],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003074515,0.00005868378,0.006290052,0.00002950444,0.0008356686,0.000002876149,0.0001038748,0.00008094292,0.9873618,0.00001111236,0.002405229,0.002512779],"study_design_scores_gemma":[0.001244833,0.0004476981,0.02660215,0.00002185882,0.001417715,0.000006859337,0.00008517988,0.005304599,0.9518057,0.0003317701,0.01223961,0.000491997],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9928036,0.002764216,0.0009531113,0.002375946,0.00001787529,0.0001281801,0.0008554102,0.00001802057,0.0000836387],"genre_scores_gemma":[0.9889202,0.0004968012,0.0009200419,0.001700861,0.0006306302,0.000012031,0.007275395,0.00001917977,0.00002482435],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0355561,"threshold_uncertainty_score":0.9644794,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01051705393605013,"score_gpt":0.220479444938514,"score_spread":0.2099623910024638,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}