{"id":"W3016141845","doi":"10.1039/d0cc01482f","title":"Synthesis and properties of an Au<sub>6</sub> cluster supported by a mixed N-heterocyclic carbene–thiolate ligand","year":2020,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Nanocluster Synthesis and Applications","field":"Materials Science","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Japan Society for the Promotion of Science; Natural Sciences and Engineering Research Council of Canada; Nagoya University; Academy of Finland","keywords":"Carbene; Cluster (spacecraft); Ligand (biochemistry); Chemistry; Combinatorial chemistry; Stereochemistry; Crystallography; Catalysis; Organic chemistry; Computer science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006746005,0.0001082414,0.0001386093,0.00007857894,0.0001918692,0.0001722242,0.0002242575,0.0002616809,0.001397779],"category_scores_gemma":[0.0001680261,0.00005988993,0.00009051892,0.0000849373,0.0001352848,0.0001060765,0.00008648488,0.0002351358,0.0003559374],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002477915,"about_ca_system_score_gemma":0.0001016412,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001332007,"about_ca_topic_score_gemma":0.002088236,"domain_scores_codex":[0.9999534,0.000003159535,0.000002926716,0.0000104757,0.00002282499,0.000007183957],"domain_scores_gemma":[0.9999228,0.00001279239,0.00001372696,0.000008749458,0.00002304564,0.00001894264],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009805147,0.00001670426,0.0001607925,0.00005134627,0.000006330361,0.00003999675,0.00001644301,0.0005493382,0.997178,0.0001369175,0.0001069538,0.001639087],"study_design_scores_gemma":[0.000007726327,0.0001787895,0.001203052,0.000002069899,0.000007369559,0.0000704572,0.00001071373,0.003727106,0.9939008,0.00003375229,0.0008537588,0.000004544985],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9971108,0.0003208703,0.0008452141,0.00006718716,0.00001152062,0.000007921517,0.0001177942,0.00004406729,0.001474467],"genre_scores_gemma":[0.9959691,0.0001074913,0.002008035,0.00001570067,0.000003314676,0.000005474502,0.0001487452,0.00001282486,0.001729318],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001397779,"threshold_uncertainty_score":0.004676044,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03429907714814453,"score_gpt":0.2408234862925331,"score_spread":0.2065244091443885,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}