{"id":"W3018469617","doi":"10.1021/acs.jpclett.0c01063","title":"Excited-State Vibronic Dynamics of Bacteriorhodopsin from Two-Dimensional Electronic Photon Echo Spectroscopy and Multiconfigurational Quantum Chemistry","year":2020,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry Letters","topic":"Photoreceptor and optogenetics research","field":"Neuroscience","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"National Institute of General Medical Sciences; Natural Sciences and Engineering Research Council of Canada; Max-Planck-Gesellschaft; Ministero dell’Istruzione, dell’Università e della Ricerca; Division of Chemistry; University of Toronto; Canada Excellence Research Chairs, Government of Canada; Human Frontier Science Program","keywords":"Bacteriorhodopsin; Excited state; Spectroscopy; Quantum chemistry; Chemistry; Vibronic spectroscopy; Echo (communications protocol); Dynamics (music); Atomic physics; Photon; Two-photon excitation microscopy; Photochemistry; Physics; Molecular physics; Quantum mechanics; Physical chemistry; Fluorescence","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002283997,0.0001899636,0.0001174461,0.0002233733,0.0001687731,0.0002770604,0.0003109299,0.0002966721,0.0005230752],"category_scores_gemma":[0.0004604103,0.0001562649,0.0001604211,0.0001859991,0.0004072842,0.00048226,0.0004222276,0.0004476923,0.00004988597],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000281583,"about_ca_system_score_gemma":0.0002754479,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008123422,"about_ca_topic_score_gemma":0.001028707,"domain_scores_codex":[0.9999512,0.000007658132,0.000002119355,0.00001080497,0.00002185334,0.000006377871],"domain_scores_gemma":[0.9999241,0.00003489819,0.00001180105,0.00001205062,0.000006104603,0.00001112036],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001414853,0.00009930792,0.002556207,0.0001470076,0.00002613633,0.0003013782,0.0002862263,0.02577053,0.9152997,0.02857891,0.00009862602,0.02669444],"study_design_scores_gemma":[0.00006678135,0.0003058813,0.02753625,0.00007315663,0.00003740419,0.0007535653,0.0001962055,0.6447868,0.2891058,0.03453363,0.002516458,0.00008805603],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9687145,0.0005729049,0.02750041,0.0001409946,0.00001821105,0.00001817922,0.00004684334,0.00004740735,0.002940606],"genre_scores_gemma":[0.9874593,0.000376367,0.01165184,0.00001635426,0.000006715413,0.00001300423,0.00006836402,0.000008260492,0.00039977],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008123422,"threshold_uncertainty_score":0.002043068,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01405291447210577,"score_gpt":0.2641397258961144,"score_spread":0.2500868114240086,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}