{"id":"W3021432129","doi":"10.1016/j.ica.2020.119726","title":"N-substituted 2-pyridinecarbothioamides and polypyridyl mixed-ligand cobalt(III)-containing complexes for photocatalytic hydrogen generation","year":2020,"lang":"en","type":"article","venue":"Inorganica Chimica Acta","topic":"Metalloenzymes and iron-sulfur proteins","field":"Energy","cited_by":9,"is_retracted":false,"has_abstract":false,"ca_institutions":"Bombardier (Canada); Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada; Old Dominion University; National Science Foundation","keywords":"Chemistry; Cobalt; Redox; Ligand (biochemistry); Moiety; Monoclinic crystal system; Catalysis; Tetrafluoroborate; Pyridine; Medicinal chemistry; Electrochemistry; Trifluoromethyl; Crystal structure; Crystallography; Inorganic chemistry; Stereochemistry; Ionic liquid; Organic chemistry; Physical chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001761766,0.0002835401,0.0002708621,0.0001103935,0.0001394603,0.000203735,0.0005038576,0.0002921731,0.0008106846],"category_scores_gemma":[0.0001612471,0.0001561423,0.0001095625,0.0001881123,0.0001669728,0.0002339272,0.000231985,0.0003455663,0.0002134809],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004191146,"about_ca_system_score_gemma":0.000208855,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009716738,"about_ca_topic_score_gemma":0.001831706,"domain_scores_codex":[0.9998634,0.0000233709,0.00001072067,0.00003244935,0.00003450067,0.00003562845],"domain_scores_gemma":[0.9999522,0.000008655716,0.00001512085,0.000005873895,0.000005501745,0.00001270774],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003375259,0.0000266793,0.00006765151,0.000182945,0.00001123212,0.00006808237,0.00003250983,0.0002120809,0.9943827,0.0003629988,0.0002174822,0.004097969],"study_design_scores_gemma":[0.00004000295,0.0002328613,0.0004227429,0.000004634331,0.00001307927,0.0001127295,0.00001137804,0.0009212474,0.9957557,0.00002375031,0.002456462,0.000005559919],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.981126,0.005380271,0.008435295,0.000142191,0.0001202766,0.00005789631,0.0001617981,0.0002847688,0.004291483],"genre_scores_gemma":[0.9939468,0.001094332,0.002624959,0.00003582698,0.00001471514,0.00002766979,0.0001089725,0.00002140249,0.002125297],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009716738,"threshold_uncertainty_score":0.00304085,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0368453432410293,"score_gpt":0.2402468498353039,"score_spread":0.2034015065942746,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}