{"id":"W3022569642","doi":"10.1039/d0cp01284j","title":"The mechanism and ligand effects of single atom rhodium supported on ZSM-5 for the selective oxidation of methane to methanol","year":2020,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Catalytic Processes in Materials Science","field":"Materials Science","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Engineering and Physical Sciences Research Council; Queen's University; Queen's University Belfast","keywords":"Rhodium; Methanol; Methane; Chemistry; Partial oxidation; Ligand (biochemistry); ZSM-5; Atom (system on chip); Anaerobic oxidation of methane; Photochemistry; Catalysis; Zeolite; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002075822,0.0001897551,0.0003492324,0.000004095722,0.00007035406,0.00004115781,0.000532568,0.00005285096,0.000002709535],"category_scores_gemma":[0.001084126,0.000122381,0.00008552291,0.0002878814,0.0003374451,0.00008583213,0.0002222322,0.00009938938,0.00000450875],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000348858,"about_ca_system_score_gemma":0.00005997434,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004564382,"about_ca_topic_score_gemma":6.371284e-8,"domain_scores_codex":[0.9986614,0.00002199524,0.000255385,0.0004083851,0.0003882413,0.0002645991],"domain_scores_gemma":[0.9972209,0.001918446,0.0002317887,0.0003067291,0.0001978329,0.0001243031],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001848663,0.0001098233,3.040162e-7,0.0004349625,0.0000172834,1.965627e-7,0.0004642715,0.00001787682,0.9971789,0.001179088,0.00006740801,0.0003450614],"study_design_scores_gemma":[0.0003057806,0.0001448217,0.000002199669,0.00003693566,0.00007366433,6.93785e-7,0.00003883792,0.0006047631,0.9773698,0.02125949,0.0000288916,0.0001341608],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9866371,0.00002251862,0.01211381,0.0005792693,0.00006191796,0.000440803,0.00004513864,0.00003121589,0.00006829199],"genre_scores_gemma":[0.9988541,0.0000030773,0.0006005798,0.000133964,0.0002912541,0.00008259121,0.000008274417,0.00001810289,0.000008027226],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0200804,"threshold_uncertainty_score":0.4990552,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01483558792464084,"score_gpt":0.2584829716808591,"score_spread":0.2436473837562182,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}