{"id":"W3022744595","doi":"10.1021/acs.joc.0c00536","title":"Design of P-Chirogenic Aminophosphine–Phosphinite Ligands at Both Phosphorus Centers: Origin of Enantioselectivities in Pd-Catalyzed Allylic Reactions","year":2020,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"European Regional Development Fund; Natural Sciences and Engineering Research Council of Canada; Conseil régional de Bourgogne-Franche-Comté; Centre National de la Recherche Scientifique; Agence Nationale de la Recherche","keywords":"Phosphinite; Phosphorus; Allylic rearrangement; Catalysis; Chemistry; Economics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005315333,0.0002493416,0.0005991505,0.00007467788,0.00006985907,0.00001325541,0.0006536811,0.0001553341,0.001347942],"category_scores_gemma":[0.0003573501,0.0001982826,0.0002564173,0.001098955,0.000141399,0.0001315382,0.0001256363,0.0004763143,0.000007233527],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002559641,"about_ca_system_score_gemma":0.0002975555,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004050416,"about_ca_topic_score_gemma":0.00000304598,"domain_scores_codex":[0.9978393,0.00002856327,0.001134462,0.0001875623,0.0005524853,0.0002576163],"domain_scores_gemma":[0.9975892,0.0003315963,0.001371032,0.0003659512,0.00018429,0.0001579723],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004637194,0.0001958584,0.001990319,0.0001750563,0.0003553909,0.00001587069,0.00151593,0.0001827159,0.9946621,0.000003037903,0.0001841977,0.0002557728],"study_design_scores_gemma":[0.001425438,0.00003921472,0.0001688729,0.0001001963,0.0002500205,0.000173669,0.001055389,0.0003571424,0.995863,0.00002720047,0.0003674885,0.0001723584],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960119,0.002296227,0.0005956462,0.0003197782,0.00003772057,0.00005752622,0.00002324509,0.00001923077,0.0006387577],"genre_scores_gemma":[0.9972901,0.001988462,0.0001113065,0.00004351725,0.00008912734,0.000001834523,0.0000157228,0.00003939692,0.0004205057],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001821446,"threshold_uncertainty_score":0.9995649,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01778930270885965,"score_gpt":0.2244565897308834,"score_spread":0.2066672870220237,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}