{"id":"W3022882252","doi":"10.1039/b005543n","title":"9 Reaction mechanisms","year":2000,"lang":"en","type":"article","venue":"Annual Reports Section B (Organic Chemistry)","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Computer science; Chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002441173,0.0004141723,0.000344099,0.00003605987,0.0002344659,0.00007104048,0.0001856915,0.0005499375,0.1449752],"category_scores_gemma":[0.0002522161,0.0004615935,0.0001908653,0.000377029,0.00005624814,0.0003575686,0.00005485504,0.0006695753,0.0003175263],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005200751,"about_ca_system_score_gemma":0.0001315147,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001407735,"about_ca_topic_score_gemma":0.000009041739,"domain_scores_codex":[0.9969947,0.00001202164,0.0007951422,0.0009708298,0.0006917824,0.0005355143],"domain_scores_gemma":[0.9981277,0.00005638879,0.0003665191,0.0009259628,0.0001703629,0.0003530795],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004617526,0.0001637861,0.00001687248,0.00006200818,0.0000460279,0.0001660212,0.0000868007,0.000004741572,0.9907765,0.00002906224,0.00198447,0.006617494],"study_design_scores_gemma":[0.000259656,0.00001672513,0.00002837939,0.00003323226,0.00004860193,0.002824645,0.0002081937,0.00002504963,0.8348771,0.002277729,0.1589898,0.0004109005],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8094292,0.00003494296,0.0006350083,0.000245319,0.0005674742,0.00009668231,0.00002171663,0.001143898,0.1878258],"genre_scores_gemma":[0.8670473,0.0000705796,0.0002277896,0.0001132785,0.0009933258,0.00004110636,0.0001799345,0.0001018261,0.1312248],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1570053,"threshold_uncertainty_score":0.9997836,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0048405125672273,"score_gpt":0.2087705599370584,"score_spread":0.2039300473698311,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}