{"id":"W3024117197","doi":"10.1021/acsenergylett.0c00714","title":"Decoupling Kinetics and Thermodynamics of Interfacial Catalysis at a Chemically Modified Black Silicon Semiconductor Photoelectrode","year":2020,"lang":"en","type":"article","venue":"ACS Energy Letters","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Canadian Institute for Advanced Research; Camille and Henry Dreyfus Foundation; Alfred P. Sloan Foundation; U.S. Department of Energy","keywords":"Semiconductor; Silicon; Catalysis; Kinetics; Nanoporous; Electrode; Materials science; Decoupling (probability); Cobalt; Chemistry; Chemical physics; Thermodynamics; Chemical engineering; Nanotechnology; Physical chemistry; Inorganic chemistry; Organic chemistry; Optoelectronics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00002248877,0.000200514,0.0003144397,0.00002723286,0.0000380119,0.00001856526,0.0002680421,0.0001124287,0.00006179343],"category_scores_gemma":[0.00003093151,0.0001948261,0.0001204222,0.0001992192,0.0001443844,0.00003585158,0.0001366917,0.0001581354,0.000002792107],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007156691,"about_ca_system_score_gemma":0.00001138593,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000590944,"about_ca_topic_score_gemma":0.00002617981,"domain_scores_codex":[0.9988323,0.000006048933,0.0003427702,0.0004047121,0.0001587858,0.000255398],"domain_scores_gemma":[0.9993489,0.00006498077,0.0001623596,0.0002571915,0.00003657384,0.0001299955],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003950714,0.00004029878,0.0001285433,0.00003721613,0.0001505991,9.728132e-7,0.000183839,0.0006218257,0.9981222,0.0001512897,0.0001925626,0.0003311718],"study_design_scores_gemma":[0.0002384659,0.00001303172,0.00000595306,0.000009423999,0.0001281467,0.00000204734,0.00001774058,0.03345125,0.965493,0.00007094985,0.000377648,0.0001923953],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9958017,0.00008847222,0.001507171,0.001987241,0.000003523103,0.0000220641,0.00001612692,0.00004496426,0.0005286623],"genre_scores_gemma":[0.9976193,0.00008921135,0.0001447876,0.001763114,0.0001031688,0.00001630134,0.0001764193,0.00002939661,0.00005824899],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03282942,"threshold_uncertainty_score":0.7944779,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009258857418244467,"score_gpt":0.2014357837391848,"score_spread":0.1921769263209404,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}