{"id":"W3026829518","doi":"10.1002/chem.202002308","title":"N‐Heterocyclic Carbenes Reduce and Functionalize Copper Oxide Surfaces in One Pot","year":2020,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Engineering and Physical Sciences Research Council; Natural Sciences and Engineering Research Council of Canada; Government of Ontario","keywords":"Carbene; Copper; Oxide; Formamide; X-ray photoelectron spectroscopy; Metal; Chemistry; Inorganic chemistry; Materials science; Polymer chemistry; Organic chemistry; Chemical engineering; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002540467,0.0004480357,0.000469851,0.00002281304,0.0002056969,0.0002066422,0.0005890287,0.0001448231,0.003914898],"category_scores_gemma":[0.0002897612,0.0004736804,0.0001623701,0.0001772437,0.0002168882,0.0001897,0.0003470569,0.001199385,0.0000578322],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001740692,"about_ca_system_score_gemma":0.00007862625,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005924168,"about_ca_topic_score_gemma":7.012152e-7,"domain_scores_codex":[0.9974448,0.00006601451,0.0008151815,0.0006772143,0.0004453856,0.0005513843],"domain_scores_gemma":[0.9984842,0.0000792141,0.0003244684,0.0003870388,0.0000806515,0.0006444545],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001174289,0.00008018197,0.003482764,0.0003092191,0.00008844315,0.0002991493,0.0003443917,0.00002658523,0.9914767,0.000001417235,0.002683086,0.001090667],"study_design_scores_gemma":[0.002762283,0.00002725816,0.001993049,0.0003256634,0.00008521574,0.002165915,0.001128097,0.0002071441,0.9643191,0.00003675617,0.02618999,0.0007594894],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9677628,0.00184826,0.00001820426,0.001171895,0.00008940016,0.0000355256,0.00002757913,0.0001155133,0.0289308],"genre_scores_gemma":[0.9954866,0.0007137487,0.0002307556,0.0004319697,0.001258916,0.000002393723,0.0000300018,0.0001139559,0.001731673],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02772377,"threshold_uncertainty_score":0.9997715,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02949233341623303,"score_gpt":0.2193356572721907,"score_spread":0.1898433238559576,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}