{"id":"W3026829518","doi":"10.1002/chem.202002308","title":"N‐Heterocyclic Carbenes Reduce and Functionalize Copper Oxide Surfaces in One Pot","year":2020,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Engineering and Physical Sciences Research Council; Natural Sciences and Engineering Research Council of Canada; Government of Ontario","keywords":"Carbene; Copper; Oxide; Formamide; X-ray photoelectron spectroscopy; Metal; Chemistry; Inorganic chemistry; Materials science; Polymer chemistry; Organic chemistry; Chemical engineering; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001190547,0.0003560335,0.0001805762,0.0001379308,0.0001459456,0.0001610109,0.0004921345,0.0002881874,0.001196113],"category_scores_gemma":[0.0001856147,0.0001573713,0.0001400255,0.0001143346,0.0001648344,0.0001727026,0.0002369958,0.0003207478,0.0003273845],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002714461,"about_ca_system_score_gemma":0.0002210753,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001251669,"about_ca_topic_score_gemma":0.003967296,"domain_scores_codex":[0.9998318,0.00001177307,0.000007996284,0.00003647515,0.0000594487,0.00005245719],"domain_scores_gemma":[0.9999237,0.00001817561,0.00002092207,0.00001491816,0.00001002169,0.00001217997],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003584452,0.00004281151,0.00009085271,0.00008011196,0.000008395577,0.00007002339,0.00004164419,0.0001298519,0.9959055,0.0002285948,0.0001936935,0.003172504],"study_design_scores_gemma":[0.000009980984,0.000106571,0.000714379,0.000002993644,0.00000505761,0.00007564226,0.00001009969,0.0004447604,0.9966772,0.0000186503,0.001930608,0.000004024031],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9864195,0.0009944239,0.004298925,0.00007010668,0.00005213325,0.00007680439,0.000183888,0.0001397431,0.007764559],"genre_scores_gemma":[0.9931391,0.0004864959,0.002871055,0.00003827661,0.0000116195,0.00003962644,0.0001171888,0.00002553853,0.003271187],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001251669,"threshold_uncertainty_score":0.004001379,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02949233341623303,"score_gpt":0.2193356572721907,"score_spread":0.1898433238559576,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}