{"id":"W3027161177","doi":"10.1139/cjc-2020-0016","title":"Catalytic Lewis and Brønsted acid <i>syn</i>-diastereoselective benzylic substitutions of <i>α</i>-hydroxy-<i>β</i>-nitro- and <i>α</i>-hydroxy-<i>β</i>-azido-alkyl arenes","year":2020,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Nitro; Catalysis; Alkyl; Alcohol; Allylic rearrangement; Brønsted–Lowry acid–base theory; Lewis acids and bases; Organic chemistry; Stereochemistry; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001918392,0.000443383,0.00081818,0.0001298391,0.0002729567,0.0001268536,0.0004712891,0.0003060426,0.0003510327],"category_scores_gemma":[0.0005188815,0.0004556458,0.0002506922,0.0004213431,0.0006714246,0.0003706803,0.00005930463,0.0006699061,0.000005155008],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001738782,"about_ca_system_score_gemma":0.001552734,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00114115,"about_ca_topic_score_gemma":0.0008447709,"domain_scores_codex":[0.9976363,0.00002455137,0.0009394873,0.0004642864,0.0003597404,0.0005756748],"domain_scores_gemma":[0.9965731,0.0001988886,0.0007028178,0.0003968152,0.0003673944,0.001760985],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000835153,0.00007588923,0.009135282,0.000788059,0.000510406,0.0002411042,0.001748592,0.0000441568,0.9806255,0.00004937611,0.002026377,0.004671707],"study_design_scores_gemma":[0.001300589,0.00006759679,0.0007000008,0.0004032892,0.0004286455,0.001679395,0.001923724,0.0001472943,0.9743147,0.0001918903,0.01827171,0.0005710933],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9756427,0.008009384,0.0000915942,0.001461165,0.00009761334,0.00009277942,0.0003813738,0.00002939309,0.01419397],"genre_scores_gemma":[0.9985536,0.0003781921,0.000117485,0.0003008895,0.0003097355,0.000007342454,0.0000431167,0.00005647759,0.0002332057],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02291083,"threshold_uncertainty_score":0.9997895,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.013186121851687,"score_gpt":0.1898238868807183,"score_spread":0.1766377650290313,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}