{"id":"W3029016285","doi":"10.1002/chem.202002150","title":"Triphenylphosphine‐Based Covalent Organic Frameworks and Heterogeneous Rh‐P‐COFs Catalysts","year":2020,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Covalent Organic Framework Applications","field":"Materials Science","cited_by":64,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ministry of Education and Child Care","funders":"Nederlandse Organisatie voor Wetenschappelijk Onderzoek; National Natural Science Foundation of China","keywords":"Hydroformylation; Phosphine; Rhodium; Triphenylphosphine; Catalysis; Covalent bond; Homogeneous; Thermal stability; Chemistry; Heterogeneous catalysis; Materials science; Combinatorial chemistry; Organic chemistry; Chemical engineering; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009907174,0.0004353516,0.0001504638,0.0002670853,0.0001641783,0.0003383716,0.0005742983,0.0003728219,0.000974938],"category_scores_gemma":[0.0001455498,0.0001640628,0.0002021146,0.0001933682,0.0002696626,0.0003354649,0.0003714086,0.0002867854,0.00031732],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003730425,"about_ca_system_score_gemma":0.0001465366,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001053544,"about_ca_topic_score_gemma":0.002081034,"domain_scores_codex":[0.9998721,0.00001272535,0.000005991643,0.00003098374,0.00004195608,0.00003627946],"domain_scores_gemma":[0.9999676,0.000005948488,0.000009527456,0.000005969896,0.000002954476,0.000007983181],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001178913,0.00006657212,0.0002529204,0.0002713073,0.00003776583,0.0005331212,0.00004809628,0.002254301,0.9744354,0.004158762,0.0004678835,0.01735589],"study_design_scores_gemma":[0.00001343823,0.0001145047,0.0004941422,0.000005046127,0.00001661214,0.000253151,0.00001615609,0.002083902,0.9896327,0.0001463866,0.007211175,0.00001269806],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9462797,0.009592985,0.02508348,0.0002403392,0.0001622412,0.0001176935,0.0004415258,0.0007121987,0.01736971],"genre_scores_gemma":[0.9906323,0.001263497,0.005403435,0.00002396402,0.00001908011,0.0000235232,0.0001087157,0.00001649851,0.002508838],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001053544,"threshold_uncertainty_score":0.003261447,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01455295246721269,"score_gpt":0.216074042876442,"score_spread":0.2015210904092293,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}