{"id":"W3029899109","doi":"10.24820/ark.5550190.p011.183","title":"Mono-endo-6-N,N-diethylcarbamoyl and bis-endo,endo-6,12-N,N-diethylcarbamoyl derivatives of Tröger’s base. Synthesis and exo-endo isomerization study","year":2020,"lang":"en","type":"article","venue":"ARKIVOC","topic":"Molecular spectroscopy and chirality","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada; Vetenskapsrådet; National Science Foundation","keywords":"Chemistry; Isomerization; Base (topology); Stereochemistry; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002010059,0.000392713,0.0002494075,0.0001641931,0.0001067024,0.0001640811,0.0004137805,0.0002886238,0.001660733],"category_scores_gemma":[0.0001792876,0.0001726287,0.0001948079,0.0001685483,0.0001171011,0.000239813,0.0001679636,0.0005577828,0.0008250629],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001842973,"about_ca_system_score_gemma":0.0001981528,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000384982,"about_ca_topic_score_gemma":0.0006949675,"domain_scores_codex":[0.9998829,0.00001351203,0.000008889371,0.00003078139,0.0000324873,0.00003126998],"domain_scores_gemma":[0.9999256,0.000006088972,0.00002077529,0.00001255367,0.00001534184,0.00001960291],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001481643,0.00005678027,0.0001120237,0.0001353705,0.00001210192,0.000151015,0.00002788977,0.0003872929,0.9916142,0.0005585913,0.0001990638,0.006597503],"study_design_scores_gemma":[0.00002470236,0.0005011571,0.0003962566,0.000006002961,0.00001265488,0.0003399711,0.00001255178,0.0005272001,0.990613,0.00005912749,0.007491793,0.00001560788],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9567607,0.00698493,0.0191636,0.0001614838,0.0001175649,0.0002201056,0.001025992,0.000195375,0.01537016],"genre_scores_gemma":[0.9705092,0.003533724,0.01730684,0.00007520855,0.00002424272,0.0001110017,0.0008014401,0.0000434123,0.007594872],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001660733,"threshold_uncertainty_score":0.005555689,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02258987125923515,"score_gpt":0.2393609942625119,"score_spread":0.2167711230032768,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}