{"id":"W3032543920","doi":"10.1002/ejoc.202000566","title":"Highly Twisted Aryl‐Anthraquinodimethanes: Synthesis, Characterization, and Fluorescence Sensing of TNT","year":2020,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Pyrene; Steric effects; Aryl; Anthracene; Fluorescence; Trinitrotoluene; Photochemistry; Electrochemistry; Perylene; Single crystal; Absorption (acoustics); Crystal structure; Combinatorial chemistry; Molecule; Organic chemistry; Crystallography; Physical chemistry; Explosive material; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001779057,0.0002966605,0.0001003917,0.0001387069,0.00007782441,0.0001321512,0.0001218375,0.0001866118,0.0005341636],"category_scores_gemma":[0.0002209031,0.00008551627,0.00006610873,0.00013838,0.0001503857,0.000160608,0.0001344046,0.0002329383,0.0002036509],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001180956,"about_ca_system_score_gemma":0.00008242073,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002256647,"about_ca_topic_score_gemma":0.0004775047,"domain_scores_codex":[0.999911,0.00001824463,0.000007959399,0.0000198122,0.00003047206,0.00001247817],"domain_scores_gemma":[0.999887,0.00002975275,0.00003381469,0.000009523474,0.00002067772,0.00001924793],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001085742,0.000003229999,0.00006017551,0.00001132721,6.593317e-7,0.00001992123,0.000008216569,0.00004403589,0.9993217,0.00003180145,0.000004369621,0.0004836181],"study_design_scores_gemma":[0.000004153108,0.0001173473,0.0007015466,0.000001265578,0.00000234378,0.00008991146,0.000007811595,0.000627296,0.9977991,0.00001423689,0.0006325376,0.000002473644],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9897929,0.0007171457,0.008024883,0.00003958493,0.00001323425,0.00003059172,0.000155241,0.00003687977,0.001189632],"genre_scores_gemma":[0.9890785,0.0006140525,0.008790776,0.00002566608,0.000008153307,0.00002880529,0.0002080495,0.00001022532,0.001235797],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005341636,"threshold_uncertainty_score":0.001787007,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01389888883586174,"score_gpt":0.2013385544144271,"score_spread":0.1874396655785654,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}