{"id":"W3034656818","doi":"10.1021/acs.organomet.0c00223","title":"Synthesis, Characterization, and Reactivity of Neutral Octahedral Alkyl-Cobalt(III) Complexes Bearing a Dianionic Pentadentate Ligand","year":2020,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Alberta Innovates - Technology Futures","keywords":"Chemistry; Protonation; Homolysis; Ligand (biochemistry); Alkyl; Reactivity (psychology); Heterolysis; Medicinal chemistry; Octahedral molecular geometry; Octahedron; Cobalt; Stereochemistry; Photochemistry; Crystallography; Crystal structure; Inorganic chemistry; Organic chemistry; Radical; Ion; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001491893,0.0002639621,0.0002746036,0.0001936702,0.0001526108,0.0004585731,0.0003170197,0.0002078302,0.0006806098],"category_scores_gemma":[0.0002441183,0.0001501846,0.00009177029,0.0002220525,0.0002221533,0.0001691036,0.0002463599,0.0002764782,0.0002468318],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004015543,"about_ca_system_score_gemma":0.0001696327,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009244555,"about_ca_topic_score_gemma":0.001507362,"domain_scores_codex":[0.9998191,0.00001962405,0.00002045021,0.00003349012,0.00006863487,0.00003860929],"domain_scores_gemma":[0.9998393,0.00002361267,0.0000404286,0.00002026811,0.00004005809,0.00003637937],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009196602,0.00001162191,0.0002190694,0.000044865,0.000005626718,0.00004146522,0.00002669843,0.00006580524,0.9982305,0.00006145229,0.00002782086,0.0011731],"study_design_scores_gemma":[0.000008577887,0.0001257254,0.0008362062,0.000002353901,0.000009683132,0.0001140278,0.00001456645,0.0002795135,0.9973598,0.0000117946,0.00123336,0.000004506804],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9949489,0.0007152104,0.002369902,0.00003166432,0.00000987761,0.00003006862,0.0001948611,0.00006446812,0.001635066],"genre_scores_gemma":[0.9955758,0.0004540357,0.002109475,0.00002049688,0.000004151378,0.0000212691,0.0004026344,0.00003295846,0.001379199],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009244555,"threshold_uncertainty_score":0.002913535,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01975803234224317,"score_gpt":0.2187893703751795,"score_spread":0.1990313380329364,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}