{"id":"W3036130097","doi":"10.1039/d0cp01771j","title":"Carbon dioxide and propane nucleation: the emergence of a nucleation barrier","year":2020,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"nanoparticles nucleation surface interactions","field":"Earth and Planetary Sciences","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung; National Science Foundation","keywords":"Nucleation; Cluster (spacecraft); Chemistry; Condensation; Thermodynamics; Chemical physics; Physical chemistry; Physics; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001043885,0.0002343462,0.0002281805,0.0001989963,0.0003124552,0.0002877588,0.0002965118,0.0001943158,0.0008272968],"category_scores_gemma":[0.000309259,0.0001344153,0.0001295655,0.0001517021,0.00039947,0.0003043607,0.0001855342,0.0002394352,0.00009546543],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006550761,"about_ca_system_score_gemma":0.0002930312,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.006640295,"about_ca_topic_score_gemma":0.005064425,"domain_scores_codex":[0.999902,0.000006078077,0.000002356298,0.00002933777,0.00003120051,0.00002896764],"domain_scores_gemma":[0.9998834,0.00006025943,0.00001954303,0.00000544268,0.00002101407,0.0000103795],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003204191,0.00003840341,0.005020221,0.0000955145,0.00001616923,0.0002620537,0.0001282116,0.003585066,0.987268,0.000900034,0.00007124708,0.002294627],"study_design_scores_gemma":[0.0000222317,0.0001461946,0.01866853,0.000006378297,0.000008135349,0.00009909192,0.00008394142,0.03210947,0.9478686,0.0003152443,0.0006579618,0.00001412191],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.997577,0.0002713112,0.0008400623,0.00002648145,0.000003668387,0.00001060595,0.00007640653,0.00001760401,0.00117682],"genre_scores_gemma":[0.9993088,0.00007229029,0.0002929768,0.000004282362,0.00000177009,0.000008469314,0.00006838534,0.000005159591,0.0002379544],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006640295,"threshold_uncertainty_score":0.01320326,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01609616133941792,"score_gpt":0.216705300571968,"score_spread":0.2006091392325501,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}