{"id":"W3036410957","doi":"10.1002/anie.202006586","title":"Palladium‐Catalyzed Cross‐Coupling of Alkenyl Carboxylates","year":2020,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":36,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Electrophile; Catalysis; Chemistry; Alkene; Carboxylate; Palladium; Catalytic cycle; Combinatorial chemistry; Coupling (piping); Base (topology); Oxidative coupling of methane; Coupling reaction; Limiting; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00008416866,0.0001847489,0.0002102413,0.00005415162,0.00007538864,0.00008826906,0.0003322909,0.0001476133,0.00213864],"category_scores_gemma":[0.0004605585,0.0002056439,0.0001777115,0.0001416677,0.0001447895,0.0003554007,0.0000991939,0.0002378528,0.00006722224],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001490267,"about_ca_system_score_gemma":0.00006747179,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001187902,"about_ca_topic_score_gemma":0.00000770468,"domain_scores_codex":[0.9985482,2.157519e-7,0.0004413872,0.0003627142,0.0004543353,0.0001931969],"domain_scores_gemma":[0.9988934,0.0001368898,0.0002668729,0.0002180598,0.0003561153,0.0001286471],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008457222,0.00006659662,0.002891917,0.00008900589,0.0001195198,0.000008026615,0.000290781,0.0004450993,0.9945125,0.0001632025,0.001262234,0.00006655858],"study_design_scores_gemma":[0.0007602589,0.000008068677,0.0006373888,0.0000729096,0.00004036938,0.00001259028,0.00012647,0.003793871,0.9911399,0.0001729787,0.003045787,0.0001893617],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9917328,0.00009939433,0.0002958759,0.00100582,0.0006505975,0.00005336524,0.0003950799,0.000169534,0.005597564],"genre_scores_gemma":[0.9955379,0.000063359,0.00004093412,0.00009884999,0.002198614,0.00002341352,0.001736633,0.00003458522,0.0002656911],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005331873,"threshold_uncertainty_score":0.9987735,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0216827883350191,"score_gpt":0.2828301950365906,"score_spread":0.2611474067015714,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}