{"id":"W3036783447","doi":"10.1021/acs.inorgchem.0c01162","title":"An NADH-Inspired Redox Mediator Strategy to Promote Second-Sphere Electron and Proton Transfer for Cooperative Electrochemical CO <sub>2</sub> Reduction Catalyzed by Iron Porphyrin","year":2020,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"CO2 Reduction Techniques and Catalysts","field":"Energy","cited_by":45,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Lawrence Berkeley National Laboratory; Canadian Institute for Advanced Research; Division of Graduate Education; University of California Berkeley","keywords":"Chemistry; Redox; Electron transfer; Catalysis; Electrochemistry; Porphyrin; Proton-coupled electron transfer; Proton; Combinatorial chemistry; Electron transport chain; Photochemistry; Inorganic chemistry; Organic chemistry; Physical chemistry; Electrode","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009266267,0.000353942,0.0001872239,0.00009064944,0.0001786124,0.0003762514,0.0003762881,0.0003094515,0.001234797],"category_scores_gemma":[0.0001376399,0.00013194,0.0000835224,0.0001346602,0.0001980448,0.0004374599,0.0003572673,0.0005759367,0.0004297282],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003237635,"about_ca_system_score_gemma":0.0001735453,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003329444,"about_ca_topic_score_gemma":0.0007104093,"domain_scores_codex":[0.9999427,0.000008569646,0.000003356744,0.00001901979,0.00001253391,0.00001386734],"domain_scores_gemma":[0.9999748,0.00000457338,0.000005664804,0.000003693735,0.000004367468,0.000006735955],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001097989,0.00007000884,0.0001775514,0.0002253562,0.00001721608,0.0002148544,0.00006651448,0.0005123888,0.9686168,0.005116337,0.0009225656,0.02395063],"study_design_scores_gemma":[0.00001781424,0.0001402458,0.0002999868,0.000006288217,0.00001136487,0.0002455222,0.00003900931,0.002843808,0.9855959,0.0003837842,0.01040663,0.000009541991],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8196829,0.007793869,0.1394767,0.001798671,0.0005326595,0.0002764297,0.0004632427,0.001028608,0.02894696],"genre_scores_gemma":[0.9704946,0.001339543,0.02281184,0.0001728423,0.00001460342,0.00004630303,0.0001083615,0.00003141517,0.004980489],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001234797,"threshold_uncertainty_score":0.00413084,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005893681235539727,"score_gpt":0.2282485279351726,"score_spread":0.2223548466996328,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}