{"id":"W3037512872","doi":"10.1002/ejoc.202000667","title":"Copper‐Promoted N‐Arylation of the Indole Side Chain of Tryptophan Using Triarylbismuthines","year":2020,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal","funders":"Natural Sciences and Engineering Research Council of Canada; Centre in Green Chemistry and Catalysis; Boehringer Ingelheim","keywords":"Chemistry; Indole test; Stereocenter; Tryptophan; Side chain; Ring (chemistry); Tripeptide; Combinatorial chemistry; Regioselectivity; Reagent; Aryl; Triethylamine; Pyridine; Stereochemistry; Organic chemistry; Catalysis; Peptide; Enantioselective synthesis; Amino acid; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0007130418,0.0001700686,0.0003626958,0.00002518462,0.00005411929,0.00001481982,0.0004821236,0.00006119756,0.002097143],"category_scores_gemma":[0.001974759,0.0001387304,0.0002287226,0.0004281251,0.0001087749,0.00008445227,0.0001500382,0.0003471111,0.000002754673],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007089914,"about_ca_system_score_gemma":0.0002542931,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000001673121,"about_ca_topic_score_gemma":9.692961e-8,"domain_scores_codex":[0.9980381,0.0001360138,0.001062543,0.0001658135,0.0004735688,0.0001239436],"domain_scores_gemma":[0.9975871,0.0001307395,0.001524846,0.0002861236,0.0003490866,0.0001221139],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001195182,0.00005602003,0.0008762659,0.0002786814,0.00008704651,0.00001506492,0.0005499365,0.0003865809,0.9967444,0.000001984444,0.0003132728,0.0005712138],"study_design_scores_gemma":[0.001570219,0.00002073501,0.0006625204,0.0002095463,0.0001062101,0.000202346,0.0003142552,0.0007530649,0.9953721,0.00002018424,0.0006479049,0.0001208967],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9912597,0.0002411047,0.003760088,0.0005185282,0.0001326693,0.00004062763,0.00002045172,0.00001719098,0.004009653],"genre_scores_gemma":[0.9974094,0.00001270913,0.001498239,0.00006643712,0.0006235799,1.027533e-7,0.00001056857,0.00005062438,0.0003283205],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006149733,"threshold_uncertainty_score":0.9988151,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03493199105959828,"score_gpt":0.2548057077702391,"score_spread":0.2198737167106409,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}