{"id":"W3038540297","doi":"10.1039/d0me00081g","title":"Synthesis, self-assembly, and air-stable radical anions of unconventional 6,7-bis-nitrated <i>N</i>-annulated perylene diimides","year":2020,"lang":"en","type":"article","venue":"Molecular Systems Design & Engineering","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"Calgary Laboratory Services; University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Canada Foundation for Innovation; University of Calgary","keywords":"Perylene; Chemistry; Photochemistry; Polymer chemistry; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001913693,0.0004552977,0.0001540819,0.00008516106,0.000114818,0.0002145986,0.0004004507,0.0002457996,0.0008681556],"category_scores_gemma":[0.0001529847,0.0001564735,0.0001548197,0.00008290488,0.0002223345,0.000292383,0.0001933232,0.000525375,0.0002486927],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000198427,"about_ca_system_score_gemma":0.0001409132,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002110546,"about_ca_topic_score_gemma":0.0004632655,"domain_scores_codex":[0.9999319,0.00000872445,0.000004860632,0.00002094538,0.00001776606,0.00001568991],"domain_scores_gemma":[0.9999202,0.000008960777,0.00003107052,0.000009372445,0.00001189745,0.00001833047],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004026266,0.0000202701,0.00005256848,0.00006063742,0.00000436026,0.00005462198,0.00004005646,0.0001950072,0.9956007,0.0007408984,0.00008848275,0.003102063],"study_design_scores_gemma":[0.00001328514,0.0001726007,0.0002832475,0.000002429693,0.000005052005,0.00009041168,0.000006778438,0.00056732,0.9956324,0.00004076771,0.003178895,0.000006826339],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9830996,0.001117281,0.01074019,0.00009538145,0.00006765428,0.0000594518,0.0001597147,0.0001505503,0.00451024],"genre_scores_gemma":[0.9817851,0.001299494,0.01169499,0.00005600377,0.00002124211,0.00005673958,0.0002270889,0.00006185901,0.004797632],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008681556,"threshold_uncertainty_score":0.002904236,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01289989701890021,"score_gpt":0.1930398755116147,"score_spread":0.1801399784927145,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}