{"id":"W3039824167","doi":"10.1021/jacs.0c06904","title":"The Cyclopropane Ring as a Reporter of Radical Leaving-Group Reactivity for Ni-Catalyzed C(sp <sup>3</sup> )–O Arylation","year":2020,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":62,"is_retracted":false,"has_abstract":true,"ca_institutions":"Vector Institute; Canadian Institute for Advanced Research; University of Toronto","funders":"Natural Resources Canada; Natural Sciences and Engineering Research Council of Canada; Tata Steel; Ontario Ministry of Research, Innovation and Science; Canada Research Chairs; University of Toronto; Office of Naval Research; Canada Foundation for Innovation; Compute Canada","keywords":"Cyclopropane; Chemistry; Reactivity (psychology); Ring (chemistry); Leaving group; Catalysis; Redox; Context (archaeology); Medicinal chemistry; Stereochemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003156529,0.0003445395,0.0001065181,0.0001054337,0.0001580323,0.0002109852,0.0003271414,0.0002589485,0.001138831],"category_scores_gemma":[0.0003674524,0.00014049,0.0001156519,0.0001301716,0.0003179353,0.0002911776,0.0001778674,0.0006722423,0.0002116879],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002466911,"about_ca_system_score_gemma":0.0002421945,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004931615,"about_ca_topic_score_gemma":0.001182748,"domain_scores_codex":[0.9998777,0.00002510521,0.000007299172,0.00002932665,0.00003657021,0.00002395855],"domain_scores_gemma":[0.9998629,0.00005297732,0.00004138934,0.00001468978,0.00001910005,0.000009030005],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001772441,0.00003420305,0.0004372499,0.0001072921,0.000008656798,0.00009691461,0.00006102205,0.0006469754,0.9918299,0.001590848,0.0002147677,0.00479484],"study_design_scores_gemma":[0.000004972115,0.00007657867,0.0002914655,0.000002388966,0.000002982946,0.000034363,0.00001266214,0.000856113,0.9976405,0.00009204289,0.0009802798,0.000005599551],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9645864,0.001544999,0.02503997,0.0003195646,0.00005072262,0.00007690147,0.0003398178,0.0001937348,0.007847792],"genre_scores_gemma":[0.9880974,0.0007196338,0.009730547,0.00005138534,0.000007258436,0.00003655684,0.0001853382,0.00001765188,0.001154227],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001138831,"threshold_uncertainty_score":0.00380981,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02086210293264739,"score_gpt":0.2844100999399513,"score_spread":0.2635479970073039,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}