{"id":"W3039926029","doi":"10.1002/ejoc.202000880","title":"Functionalization of Bis‐Diazaphospholene P–P Bonds with Diverse Electrophiles","year":2020,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saint Mary's University; Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; Killam Trusts","keywords":"Electrophile; Chemistry; Aryl; Substituent; Radical; Bond cleavage; Alkyl; Medicinal chemistry; Photochemistry; Catalysis; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001808511,0.0002362468,0.0003480021,0.0000259531,0.00006393215,0.00003284932,0.0004913082,0.0000480741,0.009630769],"category_scores_gemma":[0.0002309094,0.0002092309,0.0001224912,0.000340145,0.000102575,0.000125353,0.0001024992,0.0003507208,0.00002998276],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009299889,"about_ca_system_score_gemma":0.0002242274,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":6.963287e-7,"about_ca_topic_score_gemma":1.24205e-7,"domain_scores_codex":[0.9983773,0.00003650314,0.0006263137,0.0002332738,0.000517555,0.0002090518],"domain_scores_gemma":[0.9982975,0.00005489746,0.0008330822,0.0002633359,0.000309822,0.0002413621],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003415316,0.0001030113,0.002286702,0.0001784672,0.0001910533,0.0002244133,0.0002159684,0.00005069507,0.9935321,0.000003924803,0.002184988,0.0006871704],"study_design_scores_gemma":[0.001135134,0.0001530907,0.0003507011,0.0001381219,0.0001505917,0.0003034856,0.0003616373,0.00001448421,0.9816892,0.000005694136,0.01547719,0.0002206298],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9855409,0.000786637,0.0006939149,0.000611455,0.00004307515,0.00002221124,0.00002223355,0.00005103754,0.0122286],"genre_scores_gemma":[0.9980733,0.0001524782,0.0005738815,0.0001020883,0.000483303,2.205644e-7,0.00001469144,0.00008856948,0.0005114501],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0132922,"threshold_uncertainty_score":0.9912745,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009700268997517887,"score_gpt":0.1716158492565015,"score_spread":0.1619155802589836,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}