{"id":"W3039926029","doi":"10.1002/ejoc.202000880","title":"Functionalization of Bis‐Diazaphospholene P–P Bonds with Diverse Electrophiles","year":2020,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saint Mary's University; Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; Killam Trusts","keywords":"Electrophile; Chemistry; Aryl; Substituent; Radical; Bond cleavage; Alkyl; Medicinal chemistry; Photochemistry; Catalysis; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001566685,0.0004606081,0.0001124555,0.0002197419,0.0001351624,0.0001834869,0.0002521603,0.0002900735,0.002030073],"category_scores_gemma":[0.0002019663,0.0001336054,0.0001667655,0.000151735,0.0001598651,0.0003131032,0.0003330323,0.0004264186,0.0003910118],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001248839,"about_ca_system_score_gemma":0.0001338519,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001447234,"about_ca_topic_score_gemma":0.0003113517,"domain_scores_codex":[0.9999129,0.00001860675,0.000005640228,0.00002066367,0.00001491424,0.00002736186],"domain_scores_gemma":[0.9999309,0.00001974652,0.00001538288,0.000009307032,0.000007713344,0.00001690065],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001120623,0.00002693357,0.00008005268,0.00009489516,0.00000847921,0.0001473761,0.00004544071,0.0001747706,0.9946457,0.0005966211,0.0000731789,0.003994413],"study_design_scores_gemma":[0.00001565917,0.0002514107,0.0005401317,0.000005702841,0.000007675725,0.0001451573,0.00002021559,0.0002756234,0.9961384,0.0001361198,0.00245831,0.000005646268],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9848743,0.0009273745,0.005712308,0.00007169561,0.00003506155,0.00004388637,0.0002162554,0.00006639543,0.008052606],"genre_scores_gemma":[0.9939582,0.000680306,0.002439538,0.00003127756,0.000007391165,0.00002948554,0.0001880296,0.0000147693,0.002650987],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002030073,"threshold_uncertainty_score":0.006791294,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009700268997517887,"score_gpt":0.1716158492565015,"score_spread":0.1619155802589836,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}