{"id":"W3040357353","doi":"10.1039/d0an00946f","title":"Interactions between gold, thiol and As(<scp>iii</scp>) for colorimetric sensing","year":2020,"lang":"en","type":"article","venue":"The Analyst","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"Regional Municipality of Waterloo; National Institute for Nanotechnology; University of Waterloo","funders":"China Scholarship Council; Natural Sciences and Engineering Research Council of Canada; National Natural Science Foundation of China","keywords":"Chemistry; Thiol; Colloidal gold; Adsorption; Chelation; Divalent; Ionic strength; Dithiothreitol; Glutathione; Inorganic chemistry; Ligand (biochemistry); Combinatorial chemistry; Nuclear chemistry; Nanoparticle; Photochemistry; Organic chemistry; Nanotechnology; Biochemistry; Aqueous solution; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000284346,0.0004292934,0.0002026491,0.0002328142,0.0002756565,0.000267335,0.0003445647,0.0004973889,0.0006745302],"category_scores_gemma":[0.0002076111,0.000209973,0.0002793683,0.0001850009,0.0002275689,0.0002267755,0.000321137,0.0003256273,0.0004062477],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003522312,"about_ca_system_score_gemma":0.0002107868,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001217784,"about_ca_topic_score_gemma":0.003152577,"domain_scores_codex":[0.9997185,0.00006599736,0.00001420453,0.00006280623,0.0000950063,0.0000435202],"domain_scores_gemma":[0.9999368,0.00001831124,0.00001133013,0.000008435216,0.0000149997,0.00001013587],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002862626,0.00001264358,0.0001244937,0.0001200384,0.00001117,0.00009260255,0.00002738397,0.0001578717,0.9951038,0.0003839515,0.0002164225,0.003720978],"study_design_scores_gemma":[0.000002654474,0.00007291512,0.0003005987,0.000004272996,0.000008769885,0.0001059984,0.00001490769,0.001283737,0.9950799,0.00007342648,0.003047428,0.000005406825],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9194406,0.01165199,0.05302418,0.0009558912,0.000352903,0.0001406177,0.0002326516,0.0006644696,0.0135367],"genre_scores_gemma":[0.9647458,0.002623695,0.02325321,0.000323851,0.00003540396,0.00005454271,0.0001453969,0.00004013535,0.008778033],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001217784,"threshold_uncertainty_score":0.002555668,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02256578663498925,"score_gpt":0.2996817886066579,"score_spread":0.2771160019716686,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}