{"id":"W3041900654","doi":"10.1039/d0sc01518k","title":"Highly efficient H<sub>2</sub>S scavengers<i>via</i>thiolysis of positively-charged NBD amines","year":2020,"lang":"en","type":"article","venue":"Chemical Science","topic":"Sulfur Compounds in Biology","field":"Biochemistry, Genetics and Molecular Biology","cited_by":56,"is_retracted":false,"has_abstract":true,"ca_institutions":"Impact","funders":"National Institutes of Health; Natural Science Foundation of Beijing Municipality; National Institute of General Medical Sciences; National Natural Science Foundation of China","keywords":"Thiolysis; Chemistry; Computational chemistry; Organic chemistry; Combinatorial chemistry; Stereochemistry; Antioxidant","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002269139,0.0001767758,0.0002317588,0.00004190151,0.00008747041,0.00001670933,0.0007063742,0.0001420957,0.000008117221],"category_scores_gemma":[0.0007301915,0.0001576579,0.0001093958,0.0006984763,0.001218668,0.00000473437,0.000454681,0.000115879,0.00002644637],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003024677,"about_ca_system_score_gemma":0.0000912879,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002559791,"about_ca_topic_score_gemma":3.44084e-7,"domain_scores_codex":[0.9983058,0.00003611795,0.0002746098,0.0006854567,0.0002993268,0.0003987013],"domain_scores_gemma":[0.9990165,0.00004240407,0.0001231418,0.0003247428,0.0002530628,0.0002402085],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006621048,0.00005730447,0.0003757621,0.0000115303,0.00001451877,0.000002132792,0.00007324512,0.00003390666,0.9981833,0.00005309749,0.000147379,0.0009816648],"study_design_scores_gemma":[0.0002733795,0.0001420193,0.0004004088,0.000008599878,0.00001404762,0.0000113274,0.00002401071,0.0005820496,0.9977334,0.00002339421,0.0005946622,0.0001926692],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9966334,0.0002208911,0.001553869,0.0006515295,0.000152492,0.000117028,0.00001498446,0.00002380142,0.0006320803],"genre_scores_gemma":[0.9978328,0.00002743147,0.001270784,0.000616765,0.000198543,0.000009866296,0.0000259256,0.00001203713,0.000005867821],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001199455,"threshold_uncertainty_score":0.6429102,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009771746147454506,"score_gpt":0.2261626283912934,"score_spread":0.2163908822438388,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}