{"id":"W3042071361","doi":"10.1021/acs.analchem.0c02545","title":"Proton Transfer Reactions for the Gas-Phase Separation, Concentration, and Identification of Cardiolipins","year":2020,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Metabolomics and Mass Spectrometry Studies","field":"Biochemistry, Genetics and Molecular Biology","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Institute of General Medical Sciences; Australian Research Council; SCIEX","keywords":"Chemistry; Lipidome; Deprotonation; Population; Cardiolipins; Electrospray ionization; Mass spectrometry; Ion; Analytical Chemistry (journal); Lipidomics; Chromatography; Cardiolipin; Phospholipid; Membrane; Organic chemistry; Biochemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006756899,0.0007613871,0.0002869711,0.0003585048,0.0002900687,0.0003224122,0.0005462114,0.0007349597,0.001950323],"category_scores_gemma":[0.0007466136,0.0003164061,0.0003201151,0.0003178977,0.0003151661,0.0007729134,0.0007606529,0.001286027,0.001636011],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004231264,"about_ca_system_score_gemma":0.0003696111,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002860135,"about_ca_topic_score_gemma":0.0005555779,"domain_scores_codex":[0.9996203,0.00006572282,0.00002366611,0.0001091466,0.0001288596,0.00005225987],"domain_scores_gemma":[0.9998141,0.00006122112,0.00003822309,0.00002131941,0.00003751924,0.00002763637],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000867717,0.00003963737,0.0001395657,0.0002114514,0.00001326523,0.0001156849,0.00005223841,0.0003146035,0.9838958,0.001281505,0.0006087248,0.01324076],"study_design_scores_gemma":[0.00001602382,0.0001314676,0.0002753991,0.00001127829,0.00001042023,0.0001973432,0.00001562082,0.003487899,0.9866679,0.0002857425,0.008881885,0.00001894698],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.3865687,0.01613799,0.5789405,0.001477801,0.0006708257,0.0009963762,0.001599919,0.00231591,0.01129198],"genre_scores_gemma":[0.8369443,0.009208506,0.1464682,0.0005399671,0.0001312613,0.0004715283,0.0009965271,0.0001870021,0.005052688],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.001950323,"threshold_uncertainty_score":0.006524503,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02054944946006928,"score_gpt":0.3089830019354095,"score_spread":0.2884335524753402,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}